=234. The Destruction of Organic Matter by Moist Combustion.=—In the
process of ignition to destroy organic matter or remove ammonium salts
in the determination of potash, there are often sources of error which
may cause considerable loss. This loss, as has already been mentioned,
may arise from the volatilization of the potash salts or mechanically
from spattering. In order to avoid these causes of error de Roode
has used aqua regia both for the destruction of the ammonium salts
and for the oxidation of the organic matter at least sufficiently to
prevent any subsequent reduction of the platinum chlorid.[193] His
method consists in boiling a sample of the fertilizer, or an aliquot
portion of a solution thereof with aqua regia. The proposed method
has not yet had a sufficient experimental demonstration to warrant
its use, but analysts may find it profitable to compare this process
with the standard methods. The organic matter may also be destroyed by
combustion with sulfuric acid, as in the kjeldahl method for nitrogen.
The residue, however, contains ammonium sulfate and a large excess of
sulfuric acid, and for both reasons would not be in a fit condition for
the estimation of potash.
It is suggested that the organic matter might also be destroyed
by boiling with strong hydrochloric acid, to which from time to
time, small quantities of sodium chlorate free of potash is added.
Subsequently the solution could be boiled with addition of a little
nitric acid and the ammonium salts be removed.
POTASH IN MINERAL DEPOSITS.
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