(2) _Estimation of Potash in Guanos and Other Fertilizers containing
Organic Substances._—Ten grams of the substances are carefully
incinerated at a low temperature in a platinum dish. After ignition
the contents of the dish are placed in a half liter flask and boiled
for an hour with hydrochloric acid and a few drops of nitric acid. The
sulfuric acid can then be precipitated directly with barium chlorid, or
better, allow the flask to cool, fill to the mark, filter and treat an
aliquot part of the filtrate with barium chlorid as described above.
The filtrate from the separated sulfate of barium is neutralized with
ammonia and all the bases, with the exception of magnesia and the
alkalies, precipitated with ammonium carbonate; boil, fill to the
mark and filter. Of this filtrate evaporate from 100 to 200 cubic
centimeters in a platinum dish. After evaporation the ammonium salts
are driven off by careful ignition, the residue taken up with hot water
and filtered through as small a filter as possible into a porcelain
dish; the magnesia remaining in the precipitate. The filtrate is
acidified with a few drops of hydrochloric acid, ten cubic centimeters
of platinic chlorid added and the further determination conducted as
with kainit.
=256. Dutch Method.=—The process used at the Royal Agricultural Station
of Holland is almost identical with that employed at Halle.[205]
A. _Method for Stassfurt and other Potash Salts._—The necessary
reagents are:
1. A dilute solution of barium chlorid:
2. A solution of platinic chlorid containing one gram of platinum in
ten cubic centimeters: It must be wholly free from platinous chlorid
and nitric acid, and partially freed from an excess of hydrochloric
acid by repeated evaporations with water.
3. Alcohol of eighty per cent strength by the volume:
The methods of bringing the potash into solution and of precipitating
the sulfuric acid are the same as for the Halle process described above.
Add then twenty cubic centimeters of the platinum solution and
evaporate the mixture nearly to dryness. Add a sufficient quantity of
eighty per cent alcohol and stir for some time. Allow to stand and then
filter through a gooch dried at 120°. Finally wash with eighty per cent
alcohol, dry at 120°, and weigh.
B. _Method for Potash Superphosphate and other mixed Fertilizers._—The
reagents necessary are the same as under A, and, in addition, a
saturated solution of barium hydrate and a solution of ammonium
carbonate mixed with ammonia.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account