potassium chlorid; likewise the amount of magnesia, uncombined with
sulfuric acid, is to be reckoned as magnesium chlorid. The result of
this calculation will tell how much potash is in the form of kainit
(K₂SO₄, MgSO₄, MgCl₂ with 6H₂O) and how much of it is in the form of
schönit (K₂SO₄, MgSO₄, with 6H₂O) and how much in the form of potassium
chlorid. The sodium is reckoned as sodium chlorid.
(_c_) In calculating the contents of potash, of potassium chlorid, and
of potassium sulfate from the weighed potassium platinochlorid, the
factors 0.1928, 0.3056, and 0.3566 are used, assuming that the atomic
weight of platinum is 197.18.
(_d_) The two methods which have been described under _a_ and _b_, and
which are in common use in the Stassfurt potash industry, _i. e._, the
so-called precipitation method, and the oxalic acid method, give almost
identical results. The first method, however, deserves preference on
account of greater simplicity in cases where potash alone is to be
determined. Finkner’s method likewise gives results which agree well
with the results obtained by the customary methods. It consists in
evaporating the salt solution with a sufficient quantity of platinic
chlorid without previously removing the sulfuric acid, reducing the
potassium platinochlorid, and weighing the metallic platinum.
The following are the results of comparative analyses:
1. After the precipitation method 22.02 per cent KCl
2. After the oxalic acid method 22.03 per cent KCl
3. After Finkner’s method 22.01 per cent KCl
In another sample of carnallit the following results were obtained:
1. After the precipitation method 17.88 per cent KCl
2. After the oxalic acid method 17.88 per cent KCl
In a third sample of carnallit the content of potassium chlorid was as
follows:
1. After the precipitation method 18.44 per cent
2. After the oxalic acid method 18.38 per cent
The Anhalt chemists object to precipitating the sulfuric acid and
alkaline earths with barium oxid and ammonium carbonate, and afterwards
the potash with platinic chlorid. The results obtained with this method
are, according to them, very inaccurate, and always too low. This is
explained by the fact that it is impossible to precipitate sulfuric
acid without at the same time precipitating some of the potash, unless
it be in an acid solution.
A separation of the alkaline earths, if potash alone is to be
determined, is superfluous, for the reason that calcium and magnesium
platinochlorid are soluble in ninety per cent alcohol, even with more
facility than sodium platinochlorid.
=259. Methods for Concentrated Potash Salts.=—In the preceding
paragraphs have been given the methods used by the Stassfurt syndicate
for the estimation of potash in the raw salts as they come from the
mines. Following are the methods used by the same syndicate for the
concentrated approximately pure compounds and the other salts which
accompany them.
Public-domain text, read in full here on John Shaqi.
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