_Potassium Chlorid._—The following process is used for the estimation
of potassium and other constituents of the high grade chlorids of
commerce. In a half liter flask are placed 7.6405 grams of the finely
powdered sample, which is dissolved and made up to the mark. With
salts which contain more than half a per cent of sulfuric acid the
preliminary conversion of the sulfates into the corresponding chlorin
compounds, by precipitation with barium chlorid solution, is necessary.
Twenty cubic centimeters of the above solution, corresponding to
0.3056 gram of the salt, are placed in a flat porcelain dish having
a diameter of about ten centimeters and, after the addition of five
cubic centimeters of the platinic chlorid solution, evaporated on
the water-bath with constant stirring until, after cooling, the
sirupy liquid passes quickly into a fine crystalline condition. The
residue is rubbed into a fine powder with a glass rod, mixed with
twenty cubic centimeters of ninety-six per cent alcohol and dried at
120° to a constant weight. It is weighed while warm and brought on
a moistened filter with alcohol, care being taken that the liquid
does not touch the edge of the filter. The filtration can be carried
on under a moderate pressure. The complete washing of the potassium
platinochlorid can be easily accomplished upon the filter. The filter
and the precipitate, after as much of the alcohol wash has been removed
as is possible, are dried at 120° to constant weight and weighed while
still warm. One milligram of the potassium platinochlorid thus obtained
corresponds to a tenth per cent of potassium chlorid.
_Estimation of Sodium Chlorid._—For the estimation of the sodium
chlorid which may be present in the potassium chlorid twelve and a half
grams of the latter salt are dissolved in a quarter liter flask with
twenty-five cubic centimeters of boiling water after the addition of a
little potassium carbonate for the purpose of converting the magnesium
and calcium compounds into carbonates. After filtration 100 cubic
centimeters corresponding to five grams of the salt are evaporated to
dryness in a porcelain or platinum dish after the addition of a few
drops of concentrated hydrochloric acid in order to convert any calcium
carbonate which may be present into chlorid. The residue is gently
ignited and weighed. In this mixture of potassium and sodium chlorids
the potassium chlorid may be estimated in the usual way and the sodium
chlorid determined by difference or the respective proportions of
the two bases may be calculated after the determination of the total
chlorin by precipitation with a standard solution of silver nitrate.
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