=101. Determination of the Total Phosphoric Acid in Superphosphates
and Fertilizers.=—The process is carried on exactly as for an ordinary
phosphate, and with all the care indicated in connection with the
sampling, the incineration, the solution by means of hydrochloric acid,
and the separation of the phosphoric acid in the state of ammonium
magnesium phosphate, and finally in the titration by uranium.
=102. Determination of Soluble and Reverted Phosphoric Acid.=—To make
this determination a method unique and applicable to all cases consists
in extracting, at first, the soluble constituents in distilled water,
and following this operation by digestion in the ammonium citrate. The
products soluble in water can be determined either separately or at the
same time as the products soluble in the ammonium citrate according
to the taste of the people interested, without its being necessary to
modify very greatly the method of operation.
The determination of the soluble phosphoric acid comprises first, the
solution of the soluble constituents in distilled water; second, the
solution of the reverted phosphates in ammonium citrate; third, the
precipitation of the phosphoric acid dissolved in the two preceding
operations, and its determination.
=103. Preparation of the Sample for Analysis.=—The sample sent to the
chemical expert is prepared as has been indicated; that is to say,
it is poured on a sieve of which the meshes have a diameter of one
millimeter, and sifted upon a sheet of white paper. The parts which
do not pass the sieve are broken up either by the hand or in a mortar
and added, through the sieve, to the first portions. The product is
well mixed and, in this state, the mass presents all the homogeneity
desirable for analysis.
Some fertilizers are received in a pasty state which does not permit
of their being sifted. It is necessary in such a case to mix them
with their own weight either of precipitated calcium sulfate dried at
160° or with fine sand washed with hydrochloric acid and dried, which
divides the particles perfectly and permits of their being passed
through the meshes of the sieve.
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