=104. Extraction of the Products Soluble in Distilled Water.=—The
substance having been prepared as has just been indicated, one and a
half grams are placed in a glass mortar. Twenty cubic centimeters of
distilled water are added, and the substance gently suspended therein.
After standing for one minute, the supernatant part is decanted into a
small funnel provided with a filter-paper and placed in a flask marked
at 150 cubic centimeters. This operation is repeated five times and
is terminated by an intimate breaking up of the matter with distilled
water. When the volume of 100 cubic centimeters of the filtrate has
been obtained, the residue in the mortar is placed on the filter, and
the washing is continued until the total volume reaches 150 cubic
centimeters. The filtrate is shaken in order to render the liquor
homogeneous, and is transferred to a precipitating glass of about 300
cubic centimeters capacity.
=105. Solution of the Reverted Phosphates by Ammonium Citrate.=—The
filter from the above process is detached from the funnel and is
introduced into a flask marked at 150 cubic centimeters together with
sixty cubic centimeters of alkaline ammonium citrate prepared in the
following manner:
Pure citric acid, 400 grams.
Ammonia of 22°, 500 cubic centimeters.
The ammonia is poured upon the citric acid in the form of crystals in
a large dish. The mass becomes heated, and the solution takes place
rapidly. When it is complete and the solution is cold it is poured
into a flask of one liter capacity, and the flask is filled up to the
mark with strong ammonia. It is preserved for use in a well-stoppered
bottle. The solution must be strongly alkaline.
The flask in which the filter-paper is introduced, together with
the ammonium citrate, is stoppered and shaken violently in order to
disintegrate the filter-paper and put the reverted phosphates in
suspension. There are added then about sixty cubic centimeters of
distilled water, and the flask is shaken and left for twelve hours
at least, or at most for twenty-four hours. The volume is made up to
150 cubic centimeters with distilled water, and, after mixture, the
solution is filtered.
There are thus obtained two solutions which can be precipitated
together or separately according to circumstances. The most usual
process is to combine the two equal volumes of twenty-five, fifty, or
one hundred cubic centimeters, representing one-quarter, one-half,
or one gram of the material according to its presumed richness, in
a precipitating flask to which are added from ten to twenty cubic
centimeters of the solution of magnesia made up as follows:
Magnesium carbonate, 50 grams.
Ammonium chlorid, 100 “
Water, 500 cubic centimeters.
Hydrochloric acid, 120 “ “
After complete solution of the solid matters in the above, add 100
cubic centimeters of ammonia of 22° strength, and distilled water
enough to make one liter.
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