=137. Precipitating the Copper.=—When no more nitric acid is used than
indicated in the previous paragraph, it will not be necessary to remove
it by evaporation. The platinum dishes containing the solutions of the
cuprous oxid are arranged as shown in the figure for the precipitation
of the copper by the electric current. Each of the supporting stands
has its base covered with sheet-copper, on which the platinum dishes
rest. The uprights are made of heavy glass rods and carry the supports
for the platinum cylinders which dip into the copper solutions. The
current used is from the city service and is brought in through the
lamp shown at the right of the figure. This current has a voltage of
about 120. After passing the lamp it is conducted through the regulator
shown at the right, a glass tube closed below by a stopper carrying a
piece of platinum foil, and above by one holding a glass tube, in the
lower end of which is sealed a piece of sheet platinum connected,
through the glass tube, with the lamp. The regulating tube contains
dilute sulfuric acid. The strength of current desired is secured by
adjusting the movable pole. A battery of this kind easily secures the
precipitation of sixteen samples at once, but only twelve are shown
in the figure. The practice here is to start the operation at the
time of leaving the laboratory in the afternoon. The next morning
the deposition of the copper will be found complete. The wiring of
the apparatus is shown in the figure. The wire from the regulator is
connected with the base of the first stand, and thence passes through
the horizontal support to the base of the second, and so on. The return
to the lamp is accomplished by means of the upper wire. This plan of
arranging the apparatus has been used for two years, and with perfect
satisfaction.
Where a street current is not available, the following directions
may be followed: Use four gravity cells, such as are employed in
telegraphic work, for generating the current. This will be strong
enough for one sample and by working longer for two. Connect the
platinum dish with the zinc pole of the battery. The current is allowed
to pass until all the copper is deposited. Where a larger number of
samples is to be treated at once, the size of the battery must be
correspondingly increased.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account