In commercial grape sugar, made from starch, dextrose is the important
constituent, while in the hydrolysis of starch by a diastatic ferment,
maltose is principally produced. In the manufacture of commercial
glucose by the saccharification of starch with sulfuric acid, dextrin,
maltose, and dextrose are the dominant products, while in the similar
substance midzu ame, maltose and dextrose are chiefly found, and only a
small quantity of dextrose.[194] In honeys derived from the exudations
of coniferous trees are found also polarizing bodies not enumerated
above and presumably of a pentose character.[195] In evaporated milks
are usually found large quantities of sucrose in addition to the
natural sugar therein contained. These mixtures of carbohydrates often
present problems of great difficulty to the analyst, and the following
paragraphs will be devoted to an elucidation of the best approved
methods of solving them.
OPTICAL METHODS.
=238. Sucrose and Invert Sugar.=—The chemical methods of procedure to
be followed in the case of a sample containing both sucrose and invert
sugar have been given in sufficient detail in preceding paragraphs
(=124, 171=). When, however, it is desirable to study further the
composition of the mixture, important changes in the method are
rendered imperative. While the estimation of the sucrose and the total
invert sugar, or the sum of the dextrose and levulose, is easy of
accomplishment the separate determination of the dextrose and levulose
is not so readily secured. In the latter case the total quantity of the
two sugars may be determined, and after the destruction or removal of
one of them the other be estimated in the usual way; or in the mixture
the levulose can be determined by the variation in its gyrodynat,
caused by changes of temperature.
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