Spencer’s oven can also be used to advantage in drying viscous
liquids in a partial vacuum. For this purpose the flask A, Fig. 7,
containing the substance is made with a round bottom to resist the
atmospheric pressure. Its capacity is conveniently from 150 to 200
cubic centimeters. It is closed with a rubber stopper carrying a trap,
H Hʹ, to keep the evaporated water from falling back. The details of
the construction of the trap H are shown at the right of the figure.
The vapors enter at the lateral orifice, just above the bulb, while the
condensed water falls back into the bulb instead of into the flask A.
A series of flasks can be used at once connected through the stopcocks
G with the circular tube E leading to the vacuum. A water pump easily
exhausts the apparatus, maintaining a vacuum of about twenty-seven
inches. The hot air in the oven is kept in motion by the fan B, thus
ensuring an even temperature in every part. The flask A may be partly
filled with sand or pumice stone before the addition of the samples
to be dried, and the weight of water lost is determined by weighing
A before and after desiccation. If it be desired to introduce a slow
current of dry air or some inert gas into A, it is easily accomplished
by passing a small tube, connected with the dry air or gas supply,
through the rubber stopper and extending it into the flask as far as
possible without coming into contact with the contents.
=17. Drying Under Diminished Air Pressure.=—The temperature at which
any given body loses its volatile products is conditioned largely
by the pressure to which it is subjected. At an air pressure of 760
millimeters of mercury, water boils at 100° but it is volatilized
at all temperatures. As the pressure diminishes the temperature at
which a body loses water at a given rate falls. This is a fact of
importance to be considered in drying many agricultural products. This
is especially true of those containing oils and sugars, nearly the
whole number. Invert sugar especially is apt to suffer profound changes
at a temperature of 100°, the levulose it contains undergoing partial
decomposition. Oils are prone to oxidation and partial decomposition at
high temperatures in the presence of oxygen.
In drying in a partial vacuum therefore a double advantage is secured,
that of a lower temperature of desiccation and in presence of less
oxygen. It is not necessary to have a complete vacuum. There are few
organic products which cannot be completely deprived of their volatile
matters at a temperature of from 70° to 80° in a partial vacuum in
which the air pressure has been diminished to about one-quarter of its
normal force.
[Illustration: FIGURE 8. ELECTRIC VACUUM DRYING OVEN.]
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