=286. Expression of Specific Gravity.=—Much confusion arises in the
study of data of densities because the temperatures at which the
determinations are made are not expressed. The absolute specific
gravity would be a comparison of the weight of the object at 4°, with
water at the same temperature. It is evident that such determinations
are not always convenient, and for this reason the determinations of
density are usually made at other temperatures.
In the case of a sinker, which at 35° displaces exactly five grams of
water, the following statements may be made: One cubic centimeter of
water at 35° weighs 0.994098 gram. The volume of a sinker displacing
five grams of water at that temperature is therefore 5.0297 cubic
centimeters. This volume of water at 4° weighs 5.0297 grams. In a given
case the sinker placed in an oil at 35° is found to displace a weight
equal to 4.5725 grams corresponding to a specific gravity of 35°/35°
= 0.9145. From the foregoing data the following tabular summary is
constructed:
Weight of 5.0287 cubic centimeters of oil at 35°, 4.5725 grams.
” ” 5.0297 ” ” ” water at 35°, 5.0000 ”
” ” 5.0297 ” ” ” ” ” 4°, 5.0297 ”
Relative weight of oil at 35°, to water at 35°, 0.9145 grams.
” ” ” ” ” 35°, ” ” ” 4°, 0.9092 ”
=287. Coefficient of Expansion of Oils.=—Oils and fats of every
kind have almost the same coefficient of expansion with increasing
temperature. The coefficient of expansion is usually calculated by the
formula
_D_₀ - _D_₀ʹ
δ = ----------------
(_tʹ_ - _t_)_D_₀
in which δ represents the coefficient of expansion, _D_₀ the density at
the lowest temperature, _D_₀ʹ the density at the highest temperature,
_t_ the lowest, and _tʹ_ the highest temperatures.
In the investigations made by Crampton it was shown that the formula
would be more accurate, written as follows:[236]
_D_₀ - _D_₀ʹ
δ = ---------------------------
(_tʹ_ - _t_) × _D_₀ + _D_₀ʹ
---------------
2
The absolute densities can be calculated from the formula Δ = δ +
_K_, in which Δ represents the coefficient of absolute expansion, δ
the apparent coefficient of expansions observed in glass vessels, and
_K_ the cubical coefficient of expansion of the glass vessel. The
mean absolute coefficient of expansion for fats and oils, for 1° as
determined by experiment, is almost exactly 0.0008, and the apparent
coefficient of expansion nearly 0.00077.[237]
=288. Standard of Comparison.=—In expressing specific gravities it is
advisable to refer them always to water at 4°. The temperature at which
the observation is made should also be given. Thus the expression of
the specific gravity of lard, determined at different temperatures, is
made as follows:
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