15°.5 40°
_d_ ------ = 0.91181; _d_ ----- = 0.89679;
4° 4°
100°
and _d_ ---- = 0.85997,
4°
indicating the relative weights of the sample under examination at
15°.5, 40°, and 100°, respectively, to water at 4°.
=289. Densities of Common Fats and Oils.=—It is convenient to have at
hand some of the data representing the densities of common fats and
oils, and the following numbers are from results of determinations made
in this laboratory:[238]
15°.5 40° 100°
Temperature. _d_ = -----. _d_ = ---. _d_ = ----.
4° 4° 4°
Leaf lard 0.91181 0.89679 0.85997
Lard stearin 0.90965 0.89443 0.85750
Oleostearin 0.90714 0.89223 0.85572
Crude cottonseed oil 0.92016 0.90486 0.86739
Summer ” ” 0.92055 0.90496 0.86681
Winter ” ” 0.92179 0.90612 0.86774
Refined ” ” 0.92150 0.90573 0.86714
Compound lard ” 0.91515 0.90000 0.86289
Olive oil 0.91505 0.89965 0.86168
=290. Melting Point.=—The temperature at which fats become sensibly
liquid is a physical characteristic of some importance. Unfortunately,
the line of demarcation between the solid and liquid states of this
class of bodies is not very clear. Few of them pass _per saltum_ from
one state to the other. In most cases there is a gradual transition,
which, between its initial and final points, may show a difference
of several degrees in temperature. It has been noted, further, that
fats recently melted behave differently from those which have been
solid for several hours. For this reason it is advisable, in preparing
glycerids for the determination of their melting point, to fuse them
the day before the examination is to be made. The temperature at which
a glycerid passes from a liquid to a solid state is usually higher than
that at which it resumes its solid form. If, however, the change of
temperature could be made with extreme slowness, exposing the sample
for many hours at near its critical temperature, these differences
would be much less marked.
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