Many methods have been devised for determining the melting point of
fats, and none has been found that is satisfactory in every respect. In
some cases the moment at which fluidity occurs is assumed to be that
one when the small sample loses its opalescence and becomes clear.
In other cases the moment of fluidity is determined by the change of
shape of the sample or by observing the common phenomena presented by
a liquid body. In still other cases, the point at which the sample
becomes fluid is determined by the automatic completion of an electric
circuit, which is indicated by the ringing of a bell. This latter
process has been found very misleading in our experience. Only a few of
the proposed methods seem to demand attention here, and some of those,
depending on the visible liquefaction of a small quantity of the fat or
based on the physical property, possessed by all liquids when removed
from external stress, of assuming a spheroidal state will be described.
Other methods which may demand attention in any particular case may be
found in the works cited.[239]
=291. Determination in a Capillary Tube.=—A capillary tube is dipped
into the melted fat and when filled one end of the tube is sealed in
the lamp and it is then put aside in a cool place for twenty-four
hours. At the end of this time the tube is tied to the bulb of a
delicate thermometer the length used or filled with fat being of the
same length as the thermometer bulb. The thermometer and attached fat
are placed in water, oil, or other transparent media, and gently warmed
until the capillary column of fat becomes transparent. At this moment
the thermometric reading is made and entered as the melting point of
the fat. In comparative determinations the same length of time should
be observed in heating, otherwise discordant results will be obtained.
As in all other methods, the resulting members are comparative and not
absolute points of fusion, and the data secured by two observers on the
same sample may not agree, if different methods of preparing the fat
and different rates of fusion have been employed.
[Illustration: FIG. 83.—MELTING POINT TUBES.]
Several modifications of the method just described are practiced, and
perhaps with advantage in some cases. In one of these a small particle
of the fat is solidified in a bulb blown on a small tube, as indicated
in Fig. 83, tube _a_. The tube, in an upright position, is heated in a
convenient bath until the particle of fat just begins to run assuming
soon the position shown in tube _b_. This temperature is determined
by a thermometer, whose bulb is kept in contact with the part of the
observation tube containing the fat particle. The rise of temperature
is continued until the fat collected at the bottom of the bulb is
entirely transparent. This is called the point of complete fusion.[240]
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