=102. Formulas for Calculating Specific Rotatory Power.=—In order
to determine the specific rotatory power (gyrodynat[64]) of a given
substance it is necessary to know the specific gravity and percentage
composition or concentration of its solution, and to examine it with
monochromatic polarized light in an instrument by which the angular
rotation can be measured. The gyrodynat of any body changes with its
degree of concentration, in some cases with the temperature, and
always with the color of the light. With the red rays the gyrodynat
is least and itprogressively increases as the violet end of the
spectrum is approached. In practice the yellow ray of the spectrum
has been found most convenient for use, and in the case of sugars
the gyrodynat is always expressed either in terms of this ray or if
made with color compensating instruments in terms of the sensitive or
transition tint. In the one case the symbol used is (_a_)_{D} and in
the other (_a_)_{j}. From this statement it follows that (_a_)_{D} is
always numerically less than (_a_)_{j}. Unless otherwise specified
the gyrodynat of a body is to be considered as determined by yellow
monochromatic light, and therefore corresponds to _a__{D}.[65]
=103. Variations in Specific Rotatory Power.=—The gyrodynat of any
optically active body varies with the nature of the solvent, the
strength of the solution, and the temperature.[66]
Since water is the only solvent of importance in determining the
gyrodynat of sugars it will not be necessary here to discuss the
influence of the nature of the solvent. In respect of the strength of
the solution it has been established that in the case of cane sugar the
gyrodynat decreases while with dextrose it increases with the degree
of concentration. The influence of temperature on the gyrodynat of
common sugars is not of great importance save in the case of levulose,
where it is the most important factor, the gyrodynat rapidly increasing
as the temperature falls. It is of course understood that the above
remarks do not apply to the increase or decrease in the volume of a
solution at changed temperatures. This influence of temperature is
universally proportional to the change of volume in all cases, and
this volumetric change is completely eliminated when the polarizations
are made at the temperatures at which the solutions are completed to
standard volumes.
=104. Gyrodynatic Data for Common Sugars.=—In the case of cane sugar
the gyrodynat for twenty-five grams of sugar in 100 grams of solution
at 20° is [_a_]_{D} = 66°.37. This is about the degree of concentration
of the solutions employed in the shadow lamplight polariscopes. For
seventeen grams of sugar in 100 grams of solution the number is
[_a_]_{D} = 66°.49. This is approximately the degree of concentration
for the laurent instrument.
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