Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
A discussion of the chemical changes which occur in the Aniline Black
process, is out of place here on account of the highly involved and
complicated character of the reactions, to understand which requires a
considerable knowledge of specialized organic chemistry. But the essential
features of practical importance in the production of Aniline Black are
the following: As already noted, one of the characteristic properties of
aniline is its tendency to turn from a colorless to a dark-brown liquid in
the presence of the air. This change is due, together with certain other
causes, to an oxidation brought about by atmospheric oxygen. By employing
oxidizing agents, this oxidation can be accelerated and carried further,
and eventually the Aniline Black is obtained. Among the substances which
may be used to bring about the conversion of aniline to the insoluble
black dye are manganese dioxide, lead peroxide, hydrogen peroxide, chromic
acid, ferric salts, potassium permanganate, chloric acid and chlorates
in the presence of certain metallic salts, particularly those of vanadium
and copper. Chlorates, especially sodium chlorate and potassium chlorate,
are the most commonly employed oxidizing agents, bichromate of soda or
of potash being used, in addition, to complete the oxidation. When using
chlorates it is necessary to have present in the dye mixture a small
quantity of a metallic salt, which, while not entering into the reaction
itself, is nevertheless indispensable as an oxygen carrier. Vanadium
compounds have proved to be the most effective for this purpose, and
according to an authority, one part of vanadium salt is sufficient to
cause the conversion of 270,000 parts of aniline to Aniline Black, the
necessary amount of a chlorate being present of course. Salts of copper,
cerium, and iron are also extensively used, but they are not quite so
efficient as vanadium.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account