Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
There are several methods of applying Aniline Black on furs, the most
important being
1. One-bath Aniline Black
2. Oxidation Aniline Black
3. Diphenyl Black
4. Aniline Black by Green’s Process
1. _One-bath Aniline Black_
A typical formula for this method is the following given by Beltzer:
Aniline salt 10 kg.
Sodium chlorate 1.5 kg.
Copper sulphate 0.7 kg.
Vanadate of ammonia 10 gr.
All these substances are dissolved hot in 50 liters of water, and allowed
to cool, forming solution A. Aniline salt is aniline oil which has been
neutralized with the exact quantity of hydrochloric acid to form the
hydrochloride. It forms white or greyish crystalline lumps very easily
soluble in water. The sodium chlorate is the oxidizing agent, and the
copper sulphate and the vanadate of ammonia are the oxygen carriers.
15 kg. of sodium bichromate are also dissolved in 50 liters of water,
forming solution B. The bichromate is also an oxidizing agent and serves
to complete the oxidation of the aniline to the black.
Immediately before using, solutions A and B are mixed together, both being
cool. In general practise it is customary to mix only small quantities
at a time, as a considerable precipitate forms when the whole batch
is mixed at once, the precipitate being so much waste dye substance.
Usually a liter of A and a liter of B are mixed at a time, and the furs
brushed with the mixture. The brushing must be varied according as the
hair is hard and stiff, or soft and tender. The hair must be thoroughly
impregnated in all directions, and the penetration must not be too deep
to affect the leather. With experience and dexterity satisfactory results
can easily be achieved. After the skins have been properly treated, they
are dried at a temperature of about 35 degrees centigrade. When dry, they
are returned to the dye bench, where they receive another application
of the dye mixture, and are again dried. This operation may be repeated
as often as six or seven times before a sufficiently intense black is
obtained. Another way of producing the desired depth of shade with fewer
applications is by using more concentrated dye mixtures. Each method
has its disadvantages, the greater number of brushings requiring the
expenditure of more time and labor, and the greater concentration of
the bath resulting in a considerable loss of dye substance due to the
formation of a large precipitate when the two solutions are mixed, and
moreover, not all furs can be treated with concentrated mixtures. The best
results with this method usually require the application of six coats of
a mixture of moderate concentration.
2. _Oxidation Aniline Black_
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