Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
1. ~Sulphurous acid.~--When sulphur is burned, sulphur dioxide gas
is formed. In the presence of moisture, or when dissolved in water,
this gas forms sulphurous acid, which is one of the most commonly used
bleaching chemicals for all sorts of materials, and is very effective
for decolorizing furs. The procedure usually followed is to hang up the
moistened skins on wooden rods in a more or less cubical chamber made of
stone or brick, and lined with wood or lead. No other metals may be used,
because they are quickly corroded by the sulphurous acid. The requisite
quantity of sulphur is placed in a pot in the bleaching chamber, and then
ignited, after which the doors are shut tight. The fumes of the burning
sulphur in contact with the moist hair readily exert their bleaching
action on the furs, and the operation is allowed to proceed for six or
eight hours, or overnight. Then by means of fans or other devices, the
air filled with sulphur dioxide gas is withdrawn from the chamber, and
replaced by fresh air. The door is opened, the skins removed, exposed to
the air for a time, then rinsed, and finally dried and finished. Sometimes
one operation is not enough to sufficiently bleach the hair, so the
process is repeated. Sulphur dioxide gas can now be obtained compressed
in cylinders, which are more convenient to handle than burning sulphur.
The flow of gas which is introduced into the bleaching chamber by means
of a nozzle attached to the cylinder, can be regulated, and the bleaching
thus retarded or accelerated.
2. ~Sodium bisulphite and sodium sulphite.~--These salts of sulphurous
acid are effective in their bleaching action only when in solution in the
presence of acids. The acids liberate sulphurous acid from the salts,
so this method is virtually the same as 1. Instead of using the salts
of sulphurous acid, sulphur dioxide may be dissolved in water, and the
solution used for bleaching by immersing the furs in it. This procedure,
while consuming somewhat less time than the chamber process, is more
likely to affect the leather, which would have to be retanned. The
principle is the same as that involved in method 1.
3. ~Hydrosulphites and derivatives.~--The bleaching agent can be prepared
by adding zinc dust to commercial bisulphite of soda dissolved in about
four times its weight of water until no more reaction is evident. Milk
of lime is then added to precipitate the zinc, and the clear supernatant
liquid of 1.5°–5° Tw. is used for bleaching. The skins are immersed
for 12–24 hours, taken out, washed and finished. Instead of preparing
the hydrosulphite, the commercial products may be used with greater
convenience, a solution containing 1–4% of the hydrosulphite powder being
used, and the skins treated in this until satisfactorily bleached.
Public-domain text, read in full here on John Shaqi.
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