Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
The bleaching action of sulphurous acid and hydrosulphite is supposed to
be due to the reduction of the coloring matter of the hair to a colorless
compound; or possibly to the formation of a colorless compound of the
bleaching material with the pigment. The former seems the more probable
explanation, because the change is not a permanent one, the original
natural color returning after a long exposure of the bleached fur to air
and light. However, the results are sufficiently enduring to satisfy the
requirements of the trade in the class of furs on which these methods of
bleaching are used.
Bleaching chemicals with an oxidizing action generally used for
decolorizing furs are hydrogen peroxide and peroxides; occasionally
hypochlorites and permanganates are also used.
1. ~Hydrogen peroxide.~--Hydrogen peroxide is usually employed for
bleaching in the form of its 3% solution, to which is added about 20
cubic centimeters of ammonia per liter. The ammonia serves partially to
neutralize the acid which commercial peroxide generally contains, and
also to facilitate the bleaching action. The thoroughly degreased skins
are immersed in the solution until the hair is completely wetted by it,
are then removed, and evenly pressed or hydro-extracted, after which
the pelts are hung up to dry in the air. As the hair becomes drier,
the concentration of the peroxide becomes greater, and consequently the
bleaching action is stronger. Where there is a likelihood of the leather
being affected by the bleaching solution, the ammoniacal peroxide may
be applied to the hair with a fine sponge or brush until sufficiently
wetted, and then hanging the skins up to dry. Repetition of the process
is sometimes necessary to obtain pure white, but the results are always
excellent.
2. ~Peroxides.~--The most important of these is sodium peroxide, which
comes on the market as a yellowish-white powder, which must be kept dry,
and away from any inflammable material, as fires have been caused by the
contact of the peroxide with such substances. When dissolved in water, it
is equivalent to a strongly alkaline solution of peroxide of hydrogen.
Na₂O₂ + 2H₂O = H₂O₂ + 2NaOH
sodium water peroxide caustic
peroxide of soda
hydrogen
When dissolved in acid, the alkali is neutralized, and a neutral solution
of peroxide of hydrogen and a salt is obtained, and this method is used
to obtain peroxide of hydrogen cheaply.
Na₂O₂ + H₂SO₄ = H₂O₂ + Na₂SO₄
sulfuric sodium
acid sulphate
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