Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
3 parts of sodium peroxide are slowly dissolved in a cold 1% solution of
4 parts of sulphuric acid, stirring during the addition, and making the
resulting solution neutral to litmus paper, acid or more sodium peroxide
being added as needed. There is then added 3–6 parts of a solution
of silicate of soda of 90° Tw. The skins are immersed until properly
bleached, taken out, passed through a weak acid solution, then washed
and finished. This method generally requires the leather to be retanned
after bleaching. Another process, which involves the use of peroxides,
but which is not commonly practised, consists in rubbing the hair with
a pasty mixture of equal parts of water, barium dioxide, and silicate of
soda, hanging up the skins to dry, and then beating and brushing the hair.
3. ~Permanganates.~--The only member of this group that finds practical
application for bleaching purposes is potassium permanganate. The skins
are immersed in a 0.1% solution of the crystals of potassium permanganate,
until the hair acquires a deep brown color. They are then removed, rinsed,
and entered into a second bath containing sulphurous acid in solution,
prepared by acidifying a solution of sodium bisulphite. The skins are then
worked in this until fully bleached. It is the permanganate which does
the bleaching, the sulphurous acid being for the purpose of dissolving
the brown compound of manganese formed on the hair.
4. ~Hypochlorites.~--Chloride of lime and sodium hypochlorite, which is
prepared from the former, are the chief chemicals of this type used for
bleaching. The skins are entered into a weak solution of the hypochlorite,
and left until the hair is decolorized; then after removing, they are
passed through a dilute acid, and subsequently through a weak solution of
sodium thiosulphate in order to remove all traces of the hypochlorite.
This method causes the hair to acquire a harsh feel, and the yellow
color is never entirely eliminated. The hair, however, possesses a
great affinity for certain types of dyestuffs, and it is only when
these particular classes of dyes are to be applied to the furs, that the
hypochlorite bleach is used. (See dyeing with Acid colors).
The various oxidation methods of bleaching are supposed to change the
coloring matter of the hair into an entirely different and colorless
compound which cannot return to its original form. The bleach is therefore
permanent.
In common practise, the sulphurous acid, and the peroxide of hydrogen
methods are the two chiefly employed in bleaching processes. Sulphurous
acid is used to bleach the cheaper kinds of furs, while peroxide of
hydrogen is applied to the finer furs.
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