Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
After the furs have been treated with the solution of some alkali for the
purpose of killing the hair, they are always passed through a slightly
acidulated bath to remove any alkali which may still be adhering. This
operation must always be gone through before the skins can be mordanted
or dyed, for if it were neglected, very uneven and uncertain results
would be obtained. This process, however, entails the expenditure of
no small amount of time, labor and chemicals when large lots of skins
are being handled. In order to eliminate this extra step of “souring”
between killing and mordanting or dyeing, it has been proposed to use
alkaline mordants which combine the killing and mordanting functions,
and accomplish these two processes at the same time. The advantages of
employing such mordants are easily apparent. Cumbersome manipulation and
handling of the skins, with the attendant consumption of much time and
labor are reduced to a minimum, and besides there is no needless waste of
chemicals as is the case in the ordinary methods of killing the furs.
The principle of alkaline mordants is not a strictly new one. If it
be remembered that the old killing formulas used by the fur dyers of
an earlier age, contained metallic salts with mordanting properties in
addition to the alkaline substances, which alone were effective as killing
agents, it would seem that the suggested alkaline mordants were merely a
revival in modified form of the old processes. This is undoubtedly true
in a large measure, for the killing mixtures which the old masters used
certainly embodied the fundamental principle of simultaneous killing and
mordanting, although it was not recognized at that time.
Modern alkaline mordants have therefore been devised which can be employed
for killing and mordanting furs at the same time. They are prepared as
follows:
ALKALINE ALUMINUM MORDANT
250 grams of potassium alum are dissolved in
1 liter of boiling water. To this solution is added
300 grams of soda ash, previously dissolved in
750 c.c. of water, and the resulting precipitate is filtered off,
washed and pressed, and then dissolved in a solution of 65 grams
of caustic soda in 1 liter of water.
ALKALINE CHROMIUM MORDANT
250 c.c. of chrome acetate mordant of 20 degrees Beaumé
320 c.c. of caustic soda solution of 38 degrees Beaumé (32.5%)
10 c.c. of glycerine 30 degrees Beaumé (95%)
The solution of these substances is brought up to a volume of 1 liter by
the addition of 420 c.c. of water.
ALKALINE IRON MORDANT
138 grams ferrous sulphate are dissolved in
362 c.c. of warm water. Cool and add
25 c.c. of glycerine. Then slowly and carefully add
25.5 c.c. of concentrated ammonia, taking care that no precipitate
forms.
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