Principles and Practice of Fur Dressing and Fur DyeingAustin, William E.
Science
Principles and Practice of Fur Dressing and Fur Dyeing
Austin, William E.
Fur -- Dressing and dyeing
The most important copper salts used in fur dyeing processes are copper
sulphate, or blue vitriol, occurring in large blue crystals, very soluble
in cold and in hot water; and copper acetate, which is formed by treating
a solution of copper sulphate with a solution of the requisite quantity
of lead acetate. Copper acetate can also be obtained in the form of
blue-green crystals, very soluble in water, the solution becoming turbid
on prolonged heating, due to the formation of a greenish basic copper
acetate. This insoluble compound is known commonly as verdigris, although
it is not usually produced in the manner mentioned. Numerous fur dyeing
formulas contain verdigris, but inasmuch as the basic copper acetate is
insoluble and thus incapable of reacting with any of the substances used
in dyeing, it is assumed that the soluble normal copper acetate was meant,
for this compound is also sometimes called verdigris.
In addition, there must be mentioned here a compound which formerly found
extensive use in fur dyeing. This is a double salt of copper and iron,
analogous to alum, ferrous copper sulphate, known as blue salt. It is very
seldom used at the present time, being more effectively replaced by other
substances.
CHROMIUM MORDANTS
The typical chromium mordant is chrome alum, which is a potassium or
ammonium chromium sulphate, constituted just like the aluminum alums, and
forming crystals like these. More frequently used, nevertheless, than the
chrome alum, is chromium acetate, which is prepared from it, either by
treating a solution of the chrome alum with a solution of lead acetate,
or in the following manner:
50 grams of chrome alum are dissolved in
500 cubic centimeters of boiling water. To this is added
15 grams of 20% ammonia, diluted with 15 grams of water.
The precipitate which forms is filtered off, and preserved, the filtrate
being discarded. After thoroughly washing the residue on the filter it is
dissolved in dilute acetic acid, heating if necessary, to effect solution.
Other chromium compounds of an entirely different type are also used in
fur dyeing, these being chromates and bichromates, the latter finding
greater application than the former. Sodium bichromate is the salt most
usually employed. This forms orange-red crystals which are very soluble
in water, and in addition to its use as a mordant it also serves as an
oxidizing agent for developing or fixing certain dyes on furs.
TIN MORDANTS
Compounds of tin find only limited application in fur-dyeing, the only one
of importance being tin salts, stannous chloride, which occurs in the form
of white, hygroscopic crystals, which must be preserved in closed vessels.
It is very soluble, but in dilute solutions it readily forms a basic salt,
so stannous chloride is usually used in very concentrated solutions.
ALKALINE MORDANTS
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