It was learned that if two different metals, such as copper and
zinc amalgam, are placed in a weak acid solution (such as one part
H_{2}SO_{4} to four parts H_{2}O), and connected by a wire fastened
securely to the metals, a current of electricity (about two volts) will
pass through the wire. Carbon (a non-metal) and a metal upon which the
solution acts chemically may be used instead of two metals. There must
be chemical action between the liquid and one metal, or there will be
no current. Such a combination constitutes a _cell_, and two or
more cells make a _battery_. The current starts with the zinc,
is conducted by the solution to the copper, and thence by wire back
to the zinc, completing a _circuit_. The zinc constitutes the
negative pole (or electrode), the copper or carbon the positive pole
(or electrode).
A cell frequently employed, where a weak (about 1.1 volts) but constant
electromotive force (“E. M. F.”) is required, is one devised by the
English physicist, John D. Daniell (1790-1845). In this cell a copper
sulphate solution containing a copper electrode is placed in contact
(by means of a porous wall or partition—usually an unglazed porcelain
cup) with a zinc sulphate solution containing a zinc electrode. The
zinc electrode is negative to the copper. At each electrode there
exists a potential difference between solution and electrode.[16] The
two electrodes being connected externally by a wire, a current of
electricity will flow through the wire from the copper to the zinc, and
zinc will dissolve at the anode (positive pole) and copper deposited
on the cathode (negative pole). The current in this case, as in the
preceding, is said to be produced by _voltaic action_ and the
cell is a primary battery. Voltaic action and _electrolysis_—the
process of chemical decomposition (or dissociation of compounds or
molecules)—by the action of an electric current produced externally (as
by a dynamo) and forced through the cell, are essentially identical
phenomena, and obey the same laws.[17]
The familiar _dry cell_ contains no liquid which might be spilled,
and is very useful for certain purposes, as in automobiles, and in
operating door-bells. It is merely a voltaic cell whose chemical
contents are made practically solid (or paste-like) by the use of some
absorbent, as gelatine, sawdust, etc. In cells of the Leclanché type,
a mixture of plaster of Paris, flour, and sal ammoniac takes the place
of the solution which acts chemically upon one of the contained metals.
When used up, a dry cell must be replaced by an entirely new cell. Two
or more dry cells constitute a _dry battery_.
Public-domain text, read in full here on John Shaqi.
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