Proceedings of the California Academy of Sciences, Volume III, 1863-1867Various
Science
Proceedings of the California Academy of Sciences, Volume III, 1863-1867
Various
California Academy of Sciences -- Periodicals; Science -- Periodicals
The filtrate, or _soluble_ part, was accurately measured and
divided into four portions for analysis—two portions were used
for the determination of the iron, nickel, cobalt, phosphorus,
and alkaline earths; a third portion was employed to estimate
the copper, and the fourth portion was reserved to answer in
case of accident.
Two methods were used for the separation of the iron from the
nickel and cobalt—one by precipitation of the iron as basic
acetate, and the other by precipitation with carbonate of
baryta in the presence of an excess of chloride of ammonium;
but in neither case was the separation perfected on the first
precipitation, and traces of nickel remained with the iron
even after the second precipitation. The nickel and cobalt
were separated by means of nitrite of potash, and the cobalt
was subsequently converted into sulphate and as such weighed.
The lime and magnesia were separated by oxalate of ammonia,
care being taken to redissolve and reprecipitate the lime to
insure its being free from traces of magnesia. On spectroscopic
examination of the precipitate, it proved to be lime, free from
other alkaline earths.
The precipitate of iron, after being weighed, was fused with
carbonate of soda; the product of the fusion was dissolved in
chlorohydric acid, and the phosphoric acid precipitated with
molybdate of ammonia. This phospho-molybdic precipitate was
dissolved in ammonia to free it from possible traces of silica
and other impurities, and the phosphoric acid precipitated from
this solution by an ammoniacal mixture of sulphate of magnesia
and chloride of ammonium.
The copper was precipitated as sulphide by sulphuretted
hydrogen gas, redissolved in nitric acid, and determined as
oxyd.
The _insoluble residue_, containing free silica and
undecomposed silicate, was perfectly white, and free from all
traces of Schreibersite. It weighed 0.1855 grm. equal to 4.24
per cent. of the specimen analyzed. It was fused with carbonate
of soda, and the silica and bases determined in the usual
manner. It contained 0.159 grm. silica; 0.0054 protoxyd of
iron, with a minute trace of alumina; 0.0028 lime, and 0.0168
magnesia.
The soluble and insoluble portions gave in the analysis the
following per centage composition:
Considering the silica
to exist as olivine.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account