Pyrometry: A Practical Treatise on the Measurement of High Temperatures — John Shaqi
Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
When applied to the measurement of high temperatures, the bulb must
be made of a more infusible material than glass. Gold, porcelain,
platinum, and quartz have been used by different investigators, but
the most reliable material for temperatures exceeding 900° C. has
been found to be an alloy of platinum with 20 per cent. of rhodium.
The most suitable gas to use inside the bulb is nitrogen, which is
chemically inert towards the materials of the bulb, and is not absorbed
by the metals mechanically. When measuring high temperatures with this
instrument, a considerable pressure, amounting to 1 atmosphere for
every increase of 273 degrees above the ice point, is requisite to
prevent expansion of the nitrogen; and this pressure tends to distort
the bulb and so to falsify the indications. This trouble has been
overcome by Day, who surrounded the bulb by a second larger bulb, and
forced air or nitrogen into the intervening space until the pressure
on the exterior of the thermometer bulb was equal to that prevailing
in the interior. Even then it was not found possible to secure higher
readings than 1550° C., as the bulb commenced to alter in shape owing
to the softening of the material. This temperature represents the
highest yet measured on the gas scale; but by using a more refractory
material, such as fused zirconia, it may be found possible to extend
this range to 2000° C. or more. Experiments in this direction are
very desirable, in order that high-reading pyrometers may be checked
directly against the gas scale.
=Fixed Points for Calibration of Pyrometers.=—It is evident
that the gas thermometer is totally unsuited for use in workshops
or laboratories when a rapid determination of a high temperature is
required. Its function is to establish fixed points or temperature
standards, by means of which other instruments, more convenient to
use, may be graduated so as to agree with each other and with the gas
scale itself. The temperature scales of all modern pyrometers are thus
derived, directly or indirectly, from the gas thermometer. In the
table on next page, a number of fixed points, determined by various
observers, is given; the error, even at the highest temperatures,
probably not exceeding ±2° C.
In preparing the temperature scale of a pyrometer for practical
use, the instrument is subjected successively to a number of the
temperatures indicated in the table, and in this manner several fixed
points are established on its scale. The space between these points is
then suitably subdivided to represent intermediate temperatures.
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