Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
In certain instances, such as flues, it is necessary to use a long
instrument in a horizontal position. A rail may then be placed across
the flue, at a suitable place, to serve as a support and so to prevent
drooping.
=Liquid Element Thermocouples.=—An investigation by the author
and A. W. Grace has shown that the continuity of the E.M.F. produced
by a rising temperature is not interrupted by fusion, except in the
cases of bismuth and antimony, which both show an abrupt change in
thermo-electric properties at the melting point. It would therefore
appear feasible to measure temperatures by constructing a thermocouple
so as to retain the circuit after fusion, the advantage gained being
that the range is restricted by the boiling point of the metals instead
of the melting point and higher readings are rendered possible. The
boiling points of some of the common metals are appended:—
───────────┬───────────────────
Metal. │ Boiling Point.
───────────┼─────────┬─────────
│ Deg. C. │ Deg. F.
├─────────┼─────────
Aluminium │ 1800 │ 3270
Silver │ 1955 │ 3550
Tin │ 2270 │ 4120
Copper │ 2310 │ 4190
Nickel │ 2330 │ 4225
Iron │ 2450 │ 4440
───────────┴─────────┴─────────
From inspection of these figures, it will be seen that if a suitable
couple could be obtained, common metals might be used to measure
temperatures equalling or even exceeding the limit of the range covered
by wire junctions of metals of the platinum series. Instead of using
two metals, graphite might form one member of the couple, provided that
no objection to its use existed on other grounds.
[Illustration: FIG. 9.—LIQUID-ELEMENT THERMOCOUPLE.]
The form of thermocouple designed by the author to permit of the use of
molten elements is shown in fig. 9. A rod of refractory material, R, is
perforated longitudinally by two holes, down which are passed rods of
the thermo-elements, A and B. The lower ends of A and B are inserted in
a graphite block G, which is jointed on its upper face to R; the whole
being surrounded by the refractory cover C. On either or both of the
elements melting, the circuit is maintained through G, which serves
also to prevent the mixing of A and B when molten, whilst not affecting
the E.M.F. developed. In order to allow for the expansion of the metals
on melting, A and B are made to fit loosely in R. When inserted in a
furnace to a depth represented by EF, only the portion of the metals
adjacent to the closed end will melt, the outer parts remaining solid.
At present it has not been found possible to procure the refractory
parts in a form suited to commercial use, but when this obstacle
is overcome this type of thermocouple should prove of service for
measuring temperatures beyond the scope of ordinary base-metal
junctions.
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