Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
In making permanent temperature scales from these curves to attach
to the existing galvanometer scale, intervals of 100° may be taken
and marked opposite to the corresponding divisions on the existing
scale. Each 100° may then be equally subdivided into as many parts as
the length of scale permits, and numbered at suitable intervals. If
the junction used yield a calibration curve departing greatly from a
straight line, every 50° interval should be taken, or, if necessary,
every 25°. In the examples given both curves are nearly straight lines
in the working region, viz. 400° to 800° for the iron-constantan
junction, and 500° to 1100° for the platinum-iridioplatinum.
One precaution necessary in standardizing an indicator by this method
is to ensure that the metals used are pure, as impurities lower the
melting points. If ordered as “pure” from any dealer of repute, the
metals will generally be found satisfactory. The common salt used
should be the ordinary salt sold in blocks, and not a prepared table
salt. A second precaution, when observing melting points, is to guard
against a possible error due to the substance becoming “surfused” or
“overcooled”; in which case the temperature falls below the ordinary
freezing point before solidification commences. When freezing occurs,
however, the temperature rises to and remains at the true melting
point, and an increase of deflection following a gradual fall always
indicates overcooling. The higher deflection then attained is the true
freezing point. Antimony frequently overcools to 600° before freezing,
but on setting rises to the correct figure—631°. All metals and salts
are liable to overcooling occasionally.
=Standardization by Measurement of E.M.F.=—It has been found,
as the result of experiments, that the relation between the E.M.F.
developed by a junction and its temperature—under constant conditions
of the cold junction—may be expressed approximately by a formula as
under:—
log E = A log _t_ + B (Holman’s formula),
where E = electromotive force in microvolts, _t_ = temperature in
Centigrade degrees, and A and B are constants depending upon the
junction. With certain junctions this formula may be applied over
the working part of the scale with an error not exceeding 2° C., but
with others the discrepancy is greater. In order to determine the
constants A and B, it is necessary to measure the E.M.F. at two known
temperatures, which should be chosen as far apart as possible in the
working region. When these constants are known, a measurement of E
enables the temperature _t_ to be found by calculation.
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