Pyrometry: A Practical Treatise on the Measurement of High TemperaturesDarling, Charles R. (Charles Robert)
Science
Pyrometry: A Practical Treatise on the Measurement of High Temperatures
Darling, Charles R. (Charles Robert)
Pyrometry
In all photometric methods a standard light is employed, which should
not vary in brightness, and with which the light from the source is
compared. In optical pyrometers no attempt is made to measure the
illumination in terms of candle-power; all that is necessary is to
bring the standard and the source to the same degree of brightness
by suitable adjustments. Amongst the standards employed are
carbon-filament electric lamps, amyl-acetate lamps, and for higher
temperatures the centre of an acetylene gas-flame; each of which is
capable of producing a fixed degree of brightness when used under
specified conditions. A black body, at known temperatures, is compared
with the standard used, thus furnishing a scale of “black-body”
temperatures to which the indications of a given source may be
referred, as explained in the previous paragraph. Above 1000° C.,
however, the light becomes too dazzling to enable a proper comparison
of the standard and source to be made, and absorbing glasses must
then be used to reduce the brightness. Any coloured glass, taken at
random, might not reduce the standard and source equally; but if a
monochromatic glass be used—that is, a glass which transmits light of
one wave-length only—a well-defined relation is found to exist between
the intensity of the transmitted light and the temperature of the
source. As optical pyrometers are used for temperatures above 1000° C.
in most cases, involving the use of such glass, it will be necessary
briefly to consider the relations between the wave-lengths of light and
the temperature of the radiating substance, which in all cases will be
assumed to be a black body.
=Wien’s Law.=—When the temperature of a substance increases,
the enhanced brightness which results is shared by all parts of its
spectrum; and if the substance were viewed through a glass prism, it
would be noticed that every portion was brighter than before. Taking a
ray of wave-length λ, the relation between its intensity and the
temperature of the (black-body) source is given by Wien’s formula:—
J = _c_{1}_λ^{-5} × _e_^{-_c_{2}_/λT} (1)
where J = energy corresponding to wave-length λ; _e_ = the base of the
natural system of logarithms; T = absolute (thermodynamic) temperature
of the black-body source, and _c_{1}_ and _c_{2}_ are constants, the
values of which may be found by measuring J at two known temperatures
for light of a known wave-length. Experiment has shown that this formula
is correct for wave-lengths which lie in the visible spectrum, but does
not hold for longer waves; and modifications of Wien’s equation have
been given by Planck and others which are of more extended application.
For the purposes of optical pyrometry, however, using red light of
wave-length about 65 millionths of a centimetre, Wien’s law may be
applied with great accuracy; and a calibration based upon this law
agrees closely with the values obtained by other pyrometric methods.
Wien’s formula may be written in the form—
Public-domain text, read in full here on John Shaqi.
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