The agitation of the electrons is thus produced in a different way in
gases, and we must not apply Kirchoff's law to them, although at first
sight they appear to conform to it. We have seen that the particular
waves which an incandescent gas radiates are also absorbed by it. This
we should expect, because the particular electron which has such a
period of vibration that it sends out a certain wave-length will
naturally be in tune to exactly similar waves which fall on it, and
will so resound to them, and absorb their energy. The quantitative
law, however, that the absorbing power is exactly equal to the
radiating power, is not true for gases.
{43}
+Emission of Polarised Light.+--One very interesting result of
Kirchoff's law is the emission of polarized light by glowing tourmaline
and by one or two other crystal when they are heated to incandescence.
In ordinary light the vibrations are in all directions perpendicular to
the line along winch the light travels, that is, the vibrations at any
point are in a plane perpendicular to this line. Now any vibration in
a plane may be expressed as the sum of two component vibrations, one
component in one direction and the other in a perpendicular direction.
If we divide up the vibrations all along the wave in this way we shall
have two waves, one of which has its vibrations all in one direction
and the other in a perpendicular direction. Such waves, in which the
vibrations all lie in one plane, are said to be plane polarised.
Tourmaline is possessed of the curious property of absorbing vibrations
in one direction of the crystal much more rapidly than it does those
vibrations perpendicular to this direction, and therefore light which
passes through it emerges partially, or in some cases wholly, plane
polarised.
Since the absorbing power of tourmaline is different for the two
components, the emissive power should also be different, and that
component which was most absorbed should be radiated most strongly.
This was found to be true by Kirchoff himself, who detected and roughly
measured the polarised light emitted. Subsequently in 1902, Pflüger
carried out exact experiments which gave a beautiful confirmation of
the law.
{44}
CHAPTER V
FULL RADIATION
Public-domain text, read in full here on John Shaqi.
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