Similarly at very low temperatures the action of the light may be more
or less stable. For example, Dewar cooled a fragment of
ammonium-platino-cyanide by means of liquid hydrogen, and exposed it to
a strong light. After removing the light no phosphorescence was
observed, though at ordinary temperatures a brilliant green
phosphorescence is exhibited, but on allowing the fragment to warm up
it presently glows very brightly.
A partial stability is shown by Balmain's luminous paint, for if it be
kept in the dark until it becomes quite non-luminous it will begin to
glow again for a {63} short time if warmed up in any way. By means of
this property the infra-red region of the spectrum may be made visible.
For this purpose a screen is coated with the paint, exposed to strong
sunlight, and then placed so as to receive the spectrum. The first
effect of the invisible heat rays is to make the portions of the screen
on which they fall brighter than their surroundings; but this causes
the phosphorescence to be emitted more rapidly, and soon it is all
emitted, leaving a dark region where the heat has destroyed the
phosphorescence.
On the whole, then, those substances which phosphoresce at ordinary
temperatures do so more rapidly as the temperature rises.
But Dewar has found a number of substances which phosphoresce only at
low temperatures, _e.g._ gelatine, celluloid, paraffin, ivory and horn.
This is not a fatal objection to the idea of chemical change, as some
chemical actions will only take place at low temperatures, but it is an
objection as quite a large number of substances only phosphoresce at
low temperatures, whereas there are not many chemical reactions which
will only take place there.
As a matter of fact, even if the idea of a chemical change be the true
one, it is not a very satisfactory one, as chemical changes are
undoubtedly very complicated ones, and it would be too difficult to
trace the change from the vibration of an electron to the chemical
change, and _vice-versa_.
No satisfactory theory therefore exists to account for the absorption
and the remission of the waves, whether accompanied or unaccompanied by
a rise in temperature of the absorbing body.
{64}
CHAPTER VII
PRESSURE OF RADIATION
+Prediction of Pressure by Maxwell.+--Had the fact that light exerts a
pressure been known in Newton's time there is no doubt that it would
have been hailed as conclusive proof of the superiority of the
corpuscular theory over the wave theory. Yet, ironically enough, it
was reserved for James Clerk Maxwell to predict its existence and
calculate its value on the assumption of his electromagnetic wave
theory; and further, the measurement of its value has given decisive
evidence in favour of the wave theory, for the value predicted by the
latter is only one-half that predicted by the corpuscular theory, and
the measurements by Nicholls and Hull agree to within 1 per cent. with
the wave theory value.
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