Anhydrous radium chloride. Silver chloride. M.
I. 0·09192 0·08890 225·3
II. 0·08936 0·08627 225·8
III. 0·08839 0·08589 224·0
The mean of these numbers is 225. They were calculated in the same way
as the preceding ones by considering radium as a bivalent element, the
chloride having the formula RaCl_{2}, and taking for silver and chlorine
the values Ag = 107·8, Cl = 35·4.
Hence the atomic weight of radium is Ra = 225.
The weighings were made with a Curie aperiodic balance, perfectly
regulated, accurate to the twentieth of a milligrm. This direct reading
balance permits of very rapid weighing, a condition which is essential
in the case of the anhydrous chlorides of radium and barium, which
gradually absorb moisture, in spite of the presence of desiccating
substances in the balance. The bodies to be weighed were placed in a
platinum crucible; this crucible had been long in use, and its weight
did not vary the tenth part of a milligrm. during the course of one
operation.
The hydrated chloride obtained by crystallisation was placed in the
crucible and heated till converted into the anhydrous chloride. When the
chloride has been kept for several hours at 100° its weight becomes
constant, and does not change even if the temperature is raised to 200°.
The anhydrous chloride thus obtained constitutes, therefore, a perfectly
definite body.
The following is a series of determinations on this point. The chloride
(100 m.g.) is dried in the oven at 55°, and placed in a desiccator over
anhydrous phosphoric acid; it then gradually loses weight, which proves
that it still contains moisture; in the course of twelve hours the loss
was 3 m.g. The chloride is replaced in the stove, and the temperature
raised to 100°. During this process, the chloride lost 6·3 m.g. in
weight. After being left three hours fifteen minutes in the oven, it
lost 2·5 m.g. more. The temperature was maintained for forty-five
minutes between 100° and 120°, which caused a loss of weight of 0·1 m.g.
Then after being kept for thirty minutes at 125°, the chloride showed no
diminution in weight. Then, however, after thirty minutes at 150°, it
lost 0·1 m.g. Finally, after being heated for four hours at 200°, it
lost 0·15 m.g. During these operations the crucible varied from 0·05
m.g.
After each determination of the atomic weight, the radium was converted
into the chloride in the following manner:—To the solution containing
the weighed radium nitrate and excess of silver nitrate was added pure
hydrochloric acid; the silver chloride was filtered off; the solution
was evaporated to dryness several times with excess of pure hydrochloric
acid. In this way the nitric acid is entirely removed.
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