There is yet another form of induced radio-activity, which appears to be
produced in all bodies which have been kept for months in an active
enclosure. When these bodies are removed from the enclosure their
activity at first diminishes to a very low value according to the
ordinary law (diminution to one-half in half-an-hour); but when the
activity has fallen to about 1/20,000 of the initial value, it
diminishes no further, or at least it is dissipated very slowly,
sometimes even increasing in amount. We have sheets of copper,
aluminium, and glass which still retain a residual activity after six
months.
These phenomena of induced radio-activity appear to be of a different
kind from the ordinary ones, and show a much slower process of
evolution.
A considerable time is also necessary both for the production and
dissipation of this form of induced radio-activity.
_Radio-activity Induced upon Substances in Solution with Radium._
When a radio-active ore containing radium is treated, with the object of
extracting the radium, chemical separations are effected, after which
the radio-activity is confined entirely to one of the products. In this
way active products, which may be several hundred times as active as
uranium, are separated from totally inactive products, such as copper,
antimony, arsenic, &c. Certain other bodies (iron, lead) were never
separated in an entirely inactive state. As these active bodies are
concentrated, the case is no longer the same; each chemical separation
no longer furnishes absolutely inactive products; all the resulting
products of a separation are active in varying degrees.
After the discovery of induced radio-activity, M. Giesel was the first
to attempt to excite activity in ordinary inactive bismuth by keeping it
in solution with very active radium. He thus obtained radio-active
bismuth, and from this he concluded that the polonium extracted from
pitchblende was probably bismuth made active by the vicinity of the
radium contained in the pitchblende.
I have also prepared active bismuth by keeping bismuth in solution with
a very active radium salt.
The difficulties of this experiment consist in the extreme precautions
which must be taken to remove all traces of radium from the solution. If
we realise what an infinitesimal quantity of radium suffices to produce
very considerable radio-activity in 1 grm. of material, it is difficult
to believe in the possibility of sufficiently washing and purifying the
active product. Each purification causes a diminution of activity of the
product, whether this be due to removal of traces of radium or that the
induced radio-activity is, under these circumstances, not proof against
chemical reactions.
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