The results I obtained appear, however, to establish with certainty the
fact that the activity is produced and persists after the radium is
removed. On fractionating the nitrate of my active bismuth by
precipitation with water from the nitric acid solution, I found that
after careful purifying it fractionated like polonium, the most active
portion being precipitated first.
If the purification is not complete the opposite occurs, showing that
traces of radium still remain. I thus obtained active bismuth which from
the manner of fractionation showed great purity and which was 2000 times
as active as uranium. This bismuth diminishes in activity with lapse of
time. But another portion of the same product, prepared with the same
precautions, and fractionating in the same manner, preserves its
activity without diminution for actually a period of about three years.
This activity is 150 times as great as that of uranium.
I have also prepared active lead and silver by leaving them in solution
with radium. Generally induced radio-activity obtained in this way
scarcely lessens with lapse of time, but it does not as a rule withstand
many successive chemical changes of the active body.
M. Debierne made active barium by placing it in solution with actinium.
This barium remains active after several chemical reactions, its
activity being therefore a somewhat stable atomic property. Active
barium chloride fractionates like barium-radium chloride, the more
active portions being the least soluble in water and dilute hydrochloric
acid. The dry chloride is spontaneously luminous: its Becquerel
radiation is similar to that of barium-radium chloride. M. Debierne has
prepared an active barium chloride 1000 times as active as uranium. This
barium, however, had not acquired all the characteristics of radium, for
it showed none of the strongest radium lines in the spectroscope.
Further, its activity diminished on standing, and after three weeks it
had become one-third of its original value.
There is a wide field for research upon the radio-activity induced in
substances in solution with active bodies. It appears that, according to
the conditions of experiment, more or less stable forms of induced
atomic radio-activity may be obtained. The radio-activity induced under
these circumstances is perhaps identical with that form, which
dissipates slowly, obtained by prolonged exposure at a distance in an
active enclosure. We have reason to enquire to what degree induced
radio-activity affects the chemical nature of the atom, and if it is
able to modify the chemical properties of the latter, either temporarily
or permanently.
The chemical investigation of bodies excited at a distance is rendered
difficult by the fact that the induced activity is limited to a very
thin superficial layer, and that, consequently, only a very small
proportion of the material has been affected.
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