A determination of the amount of the charge carried off by the β rays of
radium has been made by Wien[124]. A small quantity of radium, placed in
a sealed platinum vessel, was hung by an insulating thread inside a
glass cylinder, which was exhausted to a low pressure. A connection
between the platinum vessel and an electrode sealed on to the external
glass cylinder could be made, when required, by tilting the tube. Wien
found that in a good vacuum the platinum vessel became charged to about
100 volts. The rate of escape of negative electricity from the platinum
vessel containing 4 milligrams of radium bromide corresponded to 2·91 ×
10⁻¹² amperes. If the charge on each particle is taken as 1·1 × 10⁻²⁰
electromagnetic units, this corresponds to an escape of 2·66 × 10⁷
particles per second. From 1 gram of radium bromide the corresponding
number would be 6·6 × 10⁹ per second. Since some of the β rays are
absorbed in their passage through the walls of the containing vessel and
through the radium itself, the actual number projected per second from 1
gram of radium bromide must be greater than the above value. This has
been found by the writer to be the case. The method employed reduced the
absorption of the β rays to a minimum, and the total number emitted per
second by 1 gram of radium bromide in radio-active equilibrium was found
to be 4·1 × 10¹⁰, or about six times the number found by Wien. A
detailed account of the method employed cannot be given with advantage
at this stage, but will be found later in Section 253.
=81. Determination of= _e_/_m_. We have seen (Section 50) that, in their
passage between the plates of a condenser, the cathode rays are
deflected towards the positive plate. Shortly after the discovery of the
magnetic deviation of the β rays from radium, Dorn[125] and
Becquerel[126] showed that they also were deflected by an electric
field.
By observing separately the amount of the electric and magnetic
deviation, Becquerel was able to determine the ratio of _e_/_m_ and the
velocity of the projected particles. Two rectangular copper plates, 3·45
cms. high and 1 cm. apart, were placed in a vertical plane and insulated
on paraffin blocks. One plate was charged to a high potential by means
of an influence machine, and the other was connected with earth. The
active matter was placed in a narrow groove cut in a lead plate parallel
to the copper plates and placed midway between them. The photographic
plate, enveloped in black paper, was placed horizontally above the plate
containing the active substance. The large and diffuse pencil of rays
thus obtained was deflected by the electric field, but the deviation
amounted to only a few millimetres and was difficult to measure. The
method finally adopted was to place vertically above the active matter a
thin screen of mica, which cut the field into two equal parts. Thus, in
the absence of an electric field, a narrow rectangular shadow was
produced on the plate.
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