Some time afterwards Sir William Crookes and Prof. Dewar showed that
this spectrum of nitrogen was not obtained if the radium was contained
in a highly exhausted tube. Thus it appears that the spectrum is due to
the action of the radium rays either on occluded nitrogen or the
nitrogen in the atmosphere surrounding the radium.
It is very remarkable that a phosphorescent light, like that of radium
bromide, should show a bright line spectrum of nitrogen. It shows that
radium at ordinary temperatures is able to set up radiations which are
produced only by the electric discharge under special conditions.
Sir William and Lady Huggins were led to examine the spectrum of the
natural phosphorescent light of radium with the hope that some
indications might be obtained thereby of the processes occurring in the
radium atom. Since the main radiation from radium consists of positively
charged atoms projected with great velocity, radiations must be set up
both in the expelled body and in the system from which it escapes.
[Illustration: Fig. 46a.]
Giesel[193] observed that the spectrum of the phosphorescent light of
actinium consists of three bright lines. Measurements of the wave length
were made by Hartmann[194]. The luminosity was very slight and a long
exposure was required. The lines observed were in the red, blue and
green. The wave length λ and velocity are shown below.
Line Intensity λ
1 10 4885·4 ± 0·1
Ångström units
2 6 5300 ± 6 „
3 1 5909 ± 10 „
The line 4885 was very broad; the other two lines were so feeble that it
was difficult to determine their wave length with accuracy. Hartmann
suggests that these lines may be found in the spectrum of the new stars.
The lines observed have no connection with radium or its emanation[195].
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