Both zinc sulphide and platinocyanide of barium diminish in luminosity after exposure for some time to the action of the rays. To regenerate a screen of the latter, exposure to solar light is necessary. A similar phenomenon has been observed by Villard for a screen exposed to Röntgen rays. Giesel made a screen of platinocyanide of radio-active barium. The screen, very luminous at first, gradually turned brown in colour, and at the same time the crystals became dichroic. In this condition the luminosity was much less, although the active substance had increased in activity after preparation. Many of the substances which are luminous under the rays from active substances lose this property to a large extent at low temperatures[190]. =116. Luminosity of radium compounds.= All radium compounds are spontaneously luminous. This luminosity is especially brilliant in the dry haloid salts, and persists for long intervals of time. In damp air the salts lose a large amount of their luminosity, but they recover it on drying. With very active radium chloride, the Curies have observed that the light changes in colour and intensity with time. The original luminosity is recovered if the salt is dissolved and dried. Many inactive preparations of radiferous barium are strongly luminous. The writer has seen a preparation of impure radium bromide which gave out a light sufficient to read by in a dark room. The luminosity of radium persists over a wide range of temperature and is as bright at the temperature of liquid air as at ordinary temperatures. A slight luminosity is observed in a solution of radium, and if crystals are being formed in the solution, they can be clearly distinguished in the liquid by their greater luminosity. =117. Spectrum of the phosphorescent light of radium and actinium.= Compounds of radium, with a large admixture of barium, are usually strongly self-luminous. This luminosity decreases with increasing purity, and pure radium bromide is only very feebly self-luminous. A spectroscopic examination of the slight phosphorescent light of pure radium bromide has been made by Sir William and Lady Huggins[191]. On viewing the light with a direct vision spectroscope, there were faint indications of a variation of luminosity at different points along the spectrum. In order to get a photograph of the spectrum within a reasonable time, they made use of a quartz spectroscope of special design which had been previously employed in a spectroscopic examination of faint celestial objects. After three days’ exposure with a slit of ¹⁄₄₅₀ of an inch in width, a negative was obtained which showed a number of bright lines. The magnified spectrum is shown in Fig. 46 A. The lines of this spectrum were found to agree not only in position but also in relative intensity with the band spectrum of nitrogen. The band spectrum of nitrogen and also the spark spectrum[192] of radium are shown in the same figure.