Suppose that _q₀_ particles of new matter are produced per second from a
given mass of matter. The rate of emission of energy due to the
particles produced in the time _dt_, is, at the moment of their
formation, equal to _Kq₀__dt_, where _K_ is a constant.
It is required to find the activity due to the whole matter produced
after the process has continued for a time _T_.
The activity _dI_, due to the matter produced during the time _dt_ at
the time _t_, decays according to an exponential law during the time _T_ −
_t_ that elapses before its activity is estimated, and in consequence
is given by
$$ dI = Kq₀e^{–λ (T-t)} dt $$,
where λ is the constant of decay of activity of the active matter. The
activity _I_{T}_ due to the whole matter produced in the time _T_ is
thus given by
$$ I_t = \int₀^T Kq₀e^{–λ (T-t)} dt $$
$$ = \frac {Kq₀} {λ} (1 − e^{–λ T}) $$ .
The activity reaches a maximum value _I₀_ when _T_ is very great, and is
then given by
_Kq₀_
_I₀_ = -----
λ
thus
$$ \frac {I_T} {I₀} = 1 − e^{–λ T} $$ .
This equation agrees with the experimental results for the recovery of
lost activity. Another method for obtaining this equation is given later
in section 133.
A state of equilibrium is reached when the rate of loss of activity of
the matter already produced is balanced by the activity supplied by the
production of new active matter. According to this view, the
radio-active bodies are undergoing change, but the activity remains
constant owing to the action of two opposing processes. Now, if this
active matter can at any time be separated from the substance in which
it is produced, the decay of its activity, as a whole, should follow an
exponential law with the time, since each portion of the matter
decreases in activity according to an exponential law with the time,
whatever its age may be. If _I₀_ is the initial activity of the
separated product, the activity _I_{t}_ after an interval _t_ is given
by
$$ \frac {I_T} {I₀} = e^{–λt} $$ .
Thus, the two assumptions—of uniform production of active matter and of
the decay of its activity in an exponential law from the moment of its
formation—satisfactorily explain the relation between the curves of
decay and recovery of activity.
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