In order to show that the rate of production is independent of molecular
state, temperature, etc., it is necessary in such a case to undertake a
long series of measurements extending over the whole time of recovery.
It is impossible to make accurate relative comparisons to see if the
activity is altered by the conversion of one compound into another. The
relative activity in such a case, when measured by spreading a definite
weight of material uniformly on a metal plate, varies greatly with the
physical conditions of the precipitate, although the total activity of
two compounds may be the same.
The following method[230] offers an accurate and simple means of
studying whether the rate of production of active matter is influenced
by molecular state. The substance is chemically converted into any
compound required, care being taken that active products are recovered
during the process. The new compound is then spread on a metal plate and
compared with a standard sample of uranium for several days or weeks as
required. If the rate of production of active matter is altered by the
conversion, there should be an increase or decrease of activity to a new
steady value, where the production of active matter is again balanced by
the rate of decay. This method has the great advantage of being
independent of the physical condition of the precipitate. It can be
applied satisfactorily to a compound of thorium like the nitrate and the
oxide which has been heated to a white heat, after which treatment only
a slight amount of emanation escapes. The nitrate was converted into the
oxide in a platinum crucible by treatment with sulphuric acid and
ignition to a white heat. The oxide so obtained was spread on a plate,
but no change of its activity was observed with time, showing that in
this case the rate of production was independent of molecular state.
This method, which is limited in the case of thorium, may be applied
generally to the uranium compounds where the results are not complicated
by the presence of an emanation.
No differences have yet been observed in the recovery curves of
different thorium compounds after the removal of Th X. For example, the
rate of recovery is the same whether the precipitated hydroxide is
converted into the oxide or into the sulphate.
=136. Disintegration hypothesis.= In the discussion of the changes in
radio-active bodies, only the active products Ur X and Th X have been
considered. It will, however, be shown later that these two products are
only examples of many other types of active matter which are produced by
the radio-elements, and that each of these types of active matter has
definite chemical as well as radio-active properties, which distinguish
it, not only from the other active products, but also from the substance
from which it is produced.
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