Thus de-emanation does not permanently destroy the power of thorium of
giving out an emanation, but merely produces an alteration of the amount
of the emanation which escapes from the compound.
=152. Rate of production of the emanation.= The emanating power of
thorium compounds, then, is a very variable quantity, much affected by
moisture, heat, and solution. Speaking generally, increased temperatures
and solution greatly increase the emanating power of both thorium and
radium.
The wide differences between the emanating powers of these substances in
the solid state and in solution pointed to the conclusion that the
differences were probably due to the rate of escape of the emanation
into the surrounding gas, and not to a variation of the rate of reaction
which gave rise to the emanation. It is obvious that a very slight
retardation in the rate of escape of the thorium emanation from the
compound into the gas, will, on account of the rapid decay of activity
of the emanation, produce great changes in emanating power. The
regeneration of the emanating power of de-emanated thoria and radium by
solution and chemical treatment made it evident that the original power
of thorium and radium of producing the emanation still persisted in an
unaltered degree.
The question whether the emanation was produced at the same rate in
emanating as in non-emanating compounds can be put to a sharp
quantitative test. If the rate of production of emanation goes on at the
same rate in the solid compound where very little escapes, as in the
solution where probably all escapes, the emanation must be _occluded_ in
the compound, and consequently there must be a sudden release of this
emanation on solution of the compound. On account of the very slow decay
of the activity of the emanation of radium, the effects should be far
more marked in that compound than in thorium.
From the point of view developed in section 133, the exponential law of
decay of the emanation expresses the result that _N_{t}_ the number of
particles remaining unchanged at the time _t_ is given by
$$ \frac {N_t} {N₀} = e^{–λt} $$ (1).
where _N₀_ is the initial number of particles present. When a steady
state is reached, the rate of production _q₀_ of fresh emanation
particles is exactly balanced by the rate of change of the particles
_N₀_ already present, _i.e._
_q₀_ = λ_N₀_,
_N₀_ in this case represents the amount of emanation “occluded” in the
compound. Substituting the value of λ found for the radium emanation in
section 145,
_N₀_
----- = 1/λ = 463,000.
_q₀_
The amount of emanation stored in a non-emanating radium compound should
therefore be nearly 500,000 times the amount produced per second by the
compound. This result was tested in the following way[247].
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