Runge and Precht[25] have examined the spectrum of radium in a magnetic
field, and have shown the existence of series analogous to those
observed for calcium, barium, and strontium. These series are connected
with the atomic weights of the elements in question, and Runge and
Precht have calculated by these means that the atomic weight of radium
should be 258—a number considerably greater than the number 225 obtained
by Mme Curie by means of chemical analysis. Marshall Watts[26], on the
other hand, using another relation between the lines of the spectrum,
deduced the value obtained by Mme Curie. Runge[27] has criticised the
method of deduction employed by Marshall Watts on the ground that the
lines used for comparison in the different spectra were not homologous.
Considering that the number found by Mme Curie agrees with that required
by the periodic system, it is advisable in the present state of our
knowledge to accept the experimental number rather than the one deduced
by Runge and Precht from spectroscopic evidence.
There is no doubt that radium is a new element possessing remarkable
physical properties. The detection and separation of this substance,
existing in such minute proportions in pitchblende, has been due
entirely to the characteristic property we are considering, and is the
first notable triumph of the study of radio-activity. As we shall see
later, the property of radio-activity can be used, not only as a means
of chemical research, but also as an extraordinarily delicate method of
detecting chemical changes of a very special kind.
=15. Radiations from radium.= On account of its enormous activity, the
radiations from radium are very intense: a screen of zinc sulphide,
brought near a few centigrams of radium bromide, is lighted up quite
brightly in a dark room, while brilliant fluorescence is produced on a
screen of platino-barium cyanide. An electroscope brought near the
radium salt is discharged almost instantly, while a photographic plate
is immediately affected. At a distance of one metre, a day’s exposure to
the radium rays would produce a strong impression. The radiations from
radium are analogous to those of uranium, and consist of three types of
rays: easily absorbed, penetrating, and very penetrating. Radium also
gives rise to an emanation similar to that of thorium, but with a very
much slower rate of decay. The radium emanation retains its activity for
several weeks, while that of thorium lasts only a few minutes. The
emanation obtained from a few centigrams of radium illuminates a screen
of zinc sulphide with great brilliancy. The very penetrating rays of
radium are able to light up an X ray screen in a dark room, after
passage through several centimetres of lead and several inches of iron.
Public-domain text, read in full here on John Shaqi.
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