=178.= If a platinum wire be made active by exposure to the emanation of
thoria, its activity can be removed by treating the wire with certain
acids[272]. For example, the activity is not much altered by immersing
the wire in hot or cold water or nitric acid, but more than 80% of it is
removed by dilute or concentrated solutions of sulphuric or hydrochloric
acid. The activity has not been destroyed by this treatment but is
manifested in the solution. If the solution be evaporated, the activity
remains behind on the dish.
These results show that the excited activity is due to a deposit on the
surface of bodies of _radio-active matter_ which has definite properties
as regards solution in acids. This active matter is dissolved in some
acids, but, when the solvent is evaporated, the active matter is left
behind. This active matter is deposited on the surface of bodies, for it
can be partly removed by rubbing the body with a cloth, and almost
completely by scouring the plate with sand or emery paper. If a
negatively charged wire is placed in the presence of a large quantity of
radium emanation, it becomes intensely active. If the wire, after
removal, is drawn across a screen of zinc sulphide, or willemite, a
portion of the active matter is rubbed off, and a luminous trail is left
behind on the screen. The amount of active matter deposited is extremely
small, for no difference of weight has been detected in a platinum wire
when made extremely active. On examining the wire under a microscope, no
trace of foreign matter is observed. It follows from these results that
the matter which causes excited activity is many thousand times more
active, weight for weight, than radium itself.
It is convenient to have a definite name for this radio-active matter,
for the term “excited activity” only refers to the radiation from the
active matter and not to the matter itself. The term “active deposit”
will be generally applied to this matter. The active deposit from the
three substances thorium, radium, and actinium is, in each case, derived
from its respective emanation, and possesses the same general property
of concentration on the negative electrode in an electric field and of
acting as a non-volatile type of matter which is deposited from the gas
on to the surface of bodies. These active deposits, while all soluble in
strong acids, are chemically distinct from each other.
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