The term “active deposit” can, however, only be used when the matter is
spoken of as a whole; for it will be shown later that the matter, under
ordinary conditions, is complex and contains several constituents which
have distinctive physical and chemical properties and also a distinctive
rate of change. According to the theory advanced in section 136, we may
suppose that the emanation of thorium, radium, and actinium is unstable
and breaks up with the expulsion of an α particle. The residue of the
atom of the emanation diffuses to the sides of the vessel or is removed
to the negative electrode in an electric field. This active deposit is
in turn unstable and breaks up in several successive stages.
The “excited activity” proper is the radiation set up by the active
deposit in consequence of the changes occurring in it. On this view, the
emanation is the parent of the active deposit in the same way that Th X
is the parent of the emanation. The proportionality which always exists
between the activity of the emanation and the excited activity to which
it gives rise, is at once explained, if one substance be the parent of
the other.
=179. Decay of the excited activity produced by thorium.= The excited
activity produced in a body after a _long_ exposure to the emanations of
thorium, decays in an exponential law with the time, falling to half
value in about 11 hours. The following table shows the rate of decay of
the excited activity produced on a brass rod.
Time in Current
hours
0 100
7·9 64
11·8 47·4
23·4 19·6
29·2 13·8
32·6 10·3
49·2 3·7
62·1 1·86
71·4 0·86
The results are shown graphically in Fig. 64, Curve _A_.
[Illustration: Fig. 64.]
The intensity of the radiation _I_ after any time _t_ is given by
$$ \frac {I} {I₀} = e^{–λt} $$,
where λ is the radio-active constant.
The rate of decay of excited activity, like that of the activity of
other radio-active products, is not appreciably affected by change of
conditions. The rate of decay is independent of the concentration of the
excited activity, and of the material of the body on which it is
produced. It is independent also of the nature and pressure of the gas
in which it decays. The rate of decay is unchanged whether the excited
activity is produced on the body with or without an electric field.
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