A detailed examination of the physical and chemical properties of the
active deposit of thorium has been made by F. von Lerch[282] and some
important and interesting results have been obtained. A solution of the
active deposit was prepared by dissolving the metal which had been
exposed for some time in the presence of the thorium emanation. In most
cases the active matter was precipitated with the metal. For example, an
active copper wire was dissolved in nitric acid and then precipitated by
caustic potash. The precipitate was strongly active. An active magnesium
wire, dissolved in hydrochloric acid and then precipitated as phosphate,
also gave an active precipitate. The activity of the precipitates
decayed at the normal rate, _i.e._ the activity fell to half value in
about 11 hours.
Experiments were also made on the solubility of the active deposit in
different substances. A platinum plate was made active and then placed
in different solutions, and the decrease of the activity observed. In
addition to the acids already mentioned, a large number of substances
were found to dissolve the active deposit to some extent. The active
matter was however not dissolved to an appreciable extent in ether or
alcohol. Many substances became active if added to the active solution
and then precipitated. For example, an active solution of hydrochloric
acid was obtained by dissolving the deposit on an active platinum wire.
Barium chloride was then added and precipitated as sulphate. The
precipitate was strongly active, thus suggesting that the active matter
was carried down by the barium.
=186. Electrolysis of solutions.= Dorn showed that, if solutions of
radiferous barium chloride were electrolysed, both electrodes became
temporarily active, but the anode to a greater degree than the cathode.
F. von Lerch has made a detailed examination of the action of
electrolysis on a solution of the active deposit of thorium. The matter
was dissolved off an active platinum plate by hydrochloric acid, and
then electrolysed between platinum electrodes. The cathode was very
active, but there was no trace of activity on the anode. The cathode
lost its activity at a rate much _faster_ than the normal. With an
amalgamated zinc cathode on the other hand, the rate of decay was
normal. When an active solution of hydrochloric acid was electrolysed
with an electromotive force smaller than that required to decompose
water, the platinum became active. The activity decayed to half value in
4·75 hours while the normal fall is to half value in 11 hours. These
results point to the conclusion that the active matter is complex and
consists of two parts which have different rates of decay of activity,
and can be separated by electrolysis.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account