Under special conditions it was found possible to make the anode active.
This was the case if the anion attached itself to the anode. For
example, if an active hydrochloric solution was electrolysed with a
silver anode, the chloride of silver formed was strongly active and its
activity decayed at a normal rate. The amount of activity obtained by
placing different metals in active solutions for equal times varied
greatly with the metal. For example, it was found that if a zinc plate
and an amalgamated zinc plate, which show equal potential differences
with regard to hydrochloric acid, were dipped for equal times in two
solutions of equal activity, the zinc plate was seven times as active as
the other. The activity was almost removed from the solution in a few
minutes by dipping a zinc plate into it. Some metals became active when
dipped into an active solution while others did not. Platinum,
palladium, and silver remained inactive, while copper, tin, lead,
nickel, iron, zinc, cadmium, magnesium, and aluminium became active.
These results strongly confirm the view that excited activity is due to
a deposit of active matter which has distinctive chemical behaviour.
G. B. Pegram[283] has made a detailed study of the active deposits
obtained by electrolysis of pure and commercial thorium salts. The
commercial thorium nitrate obtained from P. de Haen gave, when
electrolysed, a deposit of lead peroxide on the anode. This deposit was
radio-active, and its activity decayed at the normal rate of the excited
activity due to thorium. From solutions of pure thorium nitrate, no
visible deposit was obtained on the anode, but it was, however, found to
be radio-active. The activity decayed rapidly, falling to half value in
about one hour. Some experiments were also made on the effect of adding
metallic salts to thorium solutions and then electrolysing them. Anode
and cathode deposits of the oxides or metals obtained in this way were
found to be radio-active, but the activity fell to half value in a few
minutes. The gases produced by electrolysis were radio-active, but this
was due to the presence of the thorium emanation. The explanation of the
results obtained by Pegram and von Lerch will be considered later in
section 207. It will be shown that the active deposit of thorium
contains two distinct substances which have different rates of
transformation.
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