=187. Effect of temperature.= The activity of a platinum wire which has
been exposed in the presence of the thorium emanation is almost
completely lost by heating the wire to a white heat. Miss F. Gates[284]
found that the activity was not destroyed by the intense heat, but
manifested itself on neighbouring bodies. When the active wire was
heated electrically in a closed cylinder, the activity was transferred
from the wire to the interior surface of the cylinder in unaltered
amount. The rate of decay of the activity was not altered by the
process. By blowing a current of air through the cylinder during the
heating, a part of the active matter was removed from the cylinder.
Similar results were found for the excited activity due to radium.
F. von Lerch (_loc. cit._) determined the amount of activity removed at
different temperatures. The results are shown in the following table for
a platinum wire excited by the thorium emanation[285].
Temperature Percentage of
activity
removed
Heated 2 minutes 800° C. 0
then „ ½ minute 1020° C. 16
more
„ „ ½ „ 1260° C. 52
„
„ „ ½ „ 1460° C. 99
„
The effect of heat on the volatilization of the active deposit of radium
has been examined in detail by Curie and Danne. The interesting and
important results obtained by them will be discussed in chapter XI,
section 226.
=188. Effect of variation of E.M.F. on amount of excited activity from
thorium.= It has been shown that the excited activity is confined to
the cathode in a strong electric field. In weaker fields the activity
is divided between the cathode and the walls of the vessel. This was
tested in an apparatus[286] shown in Fig. 70.
[Illustration: Fig. 70.]
_A_ is a cylindrical vessel of 5·5 cms. diameter, _B_ the negative
electrode passing through insulating ends _C_, _D_. For a potential
difference of 50 volts, most of the excited activity was deposited on
the electrode _B_. For about 3 volts, half of the total excited activity
was produced on the rod _B_, and half on the walls of the vessel.
Whatever the voltage applied, the sum of the activities on the central
rod and the walls of the cylinder was found to be a constant when a
steady state was reached.
When no voltage was applied, diffusion alone was operative, and in that
case about 13 per cent. of the total activity was on the rod _B_. The
application of an electric field has thus no influence on the sum total
of excited activity, but merely controls the proportion concentrated on
the negative electrode.
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