It has been shown in sections 127 and 129 that a radio-active
constituent Ur X can be separated from uranium by several different
processes. The activity of the separated Ur X decays with the time,
falling to half value in about 22 days. At the same time the uranium,
from which the Ur X has been separated, gradually regains its lost
activity. The laws of decay of Ur X and of the recovery of the lost
activity of the uranium are expressed by the equations
$$ \frac {I} {I₀} = e^{–λt} $$,
and
$$ \frac {I_t} {I₀} = 1 − e^{–λt} $$,
where λ is the radio-active constant of Ur X. The substance Ur X is
produced from uranium at a constant rate, and the constant
radio-activity observed in uranium represents a state of equilibrium,
where the rate of production of new active matter is balanced by the
rate of change of the Ur X already produced.
The radio-active processes occurring in uranium present several points
of difference from the processes occurring in thorium and radium. In the
first place, uranium does not give off an emanation, and in consequence
does not produce any excited activity on bodies. So far only one active
product Ur X has been observed in uranium. This active product Ur X
differs from Th X and the emanations, inasmuch as the radiation from it
consists almost entirely of β rays. This peculiarity of the radiations
from Ur X initially led to some confusion in the interpretation of
observations on Ur X and the uranium from which it had been separated.
When examined by the photographic method, the uranium freed from Ur X
showed no activity, while the Ur X possessed it to an intense degree.
With the electric method, on the other hand, the results obtained were
exactly the reverse. The uranium freed from Ur X showed very little loss
of activity, while the activity of the Ur X was very small. The
explanation of these results was given by Soddy[296] and by Rutherford
and Grier[297]. The α rays of uranium are photographically almost
inactive, but produce most of the ionization in the gas. The β rays, on
the other hand, produce a strong photographic action, but very little
ionization compared with the α rays. When the Ur X is separated from the
uranium, the uranium does not at first give out any β rays. In the
course of time fresh Ur X is produced from the uranium, and β rays begin
to appear, gradually increasing in intensity until they reach the
original value shown before the separation of the Ur X.
In order to determine the recovery curves of uranium after the
separation of Ur X, it was thus necessary to measure the rate of
increase of the β rays. This was done by covering the uranium with a
layer of aluminium of sufficient thickness to absorb all the α rays, and
then measuring the ionization due to the rays in an apparatus similar to
Fig. 17.
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