Uranium has not yet been obtained inactive when tested by the electric
method. Becquerel[298] has stated that he was able to obtain inactive
uranium, but in his experiments the uranium was covered with a layer of
black paper, which would entirely absorb the α rays. There is no
evidence that the α radiation of uranium has been altered either in
character or amount by any chemical treatment. The α rays appear to be
inseparable from the uranium, and it will be shown later that thorium
and radium as well as uranium also possess a non-separable activity
consisting entirely of α rays. The changes occurring in uranium must
then be considered to be of two kinds, (1) the change which gives rise
to the α rays and the product Ur X, (2) the change which gives rise to
the β rays from Ur X.
The possibility of separating the Ur X, which gives rise to the β rays
of uranium, shows that the α and β rays are produced quite independently
of one another, and by matter of different chemical properties.
Following the general considerations discussed in section 136 we may
suppose that every second some of the atoms of uranium—a very minute
fraction of the total number present will suffice—become unstable and
break up, expelling an α particle with great velocity. The uranium atom,
minus one α particle, becomes the atom of the new substance, Ur X. This
in turn is unstable and breaks up with the expulsion of the β particle
and the appearance of a γ ray.
The changes occurring in uranium are graphically shown in Fig. 77.
[Illustration: Fig. 77.]
On this view the α ray activity of uranium should be an inherent
property of the uranium, and should be non-separable from it by physical
or chemical means. The β and γ ray activity of uranium is a property of
Ur X, which differs in chemical properties from the parent substance and
can at any time be completely removed from it. The final product, after
the decay of Ur X, is so slightly active that its activity has not yet
been observed. We shall see later (chapter XIII.) that there is some
reason to believe that the changes in uranium do not end at this point
but continue through one or more stages, finally giving rise to radium,
or in other words that radium is a product of the disintegration of the
uranium atom. Meyer and Schweidler[299], in a recent paper, state that
the activity due to uranium preparations increases somewhat in a closed
vessel. On removing the uranium no residual activity, however, was
observed. They consider that this effect may be due to a very
short-lived emanation emitted by uranium.
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