It will be shown later that the variation with time of the activity,
imparted to a body by a short exposure, is expressed by an equation of
the above form. It thus remains to fix the values of λ₁, λ₂. Since the
above equation is symmetrical with regard to λ₁, λ₂, it is not possible
to settle from the agreement of the theoretical and experimental curve
which value of λ refers to the first change. The curve of variation of
activity with time is unaltered if the values of λ₁ and λ₂ are
interchanged.
It is found experimentally that the activity 5 or 6 hours after removal
decays very approximately according to an exponential law with the time,
falling to half value in 11 hours. This is the normal rate of decay of
thorium for all times of exposure, provided measurements are not begun
until several hours after the removal of the active body from the
emanation.
This fixes the value of the constants of one of the changes. Let us
assume for the moment that this gives the value of λ₁.
Then λ₁ = 1·75 × 10⁻⁵ (sec)⁻¹.
Since the maximum activity is reached after an interval _T_ = 220
minutes (see Fig. 65), substituting the values of λ₁ and _T_ in the
equation, the value of λ₂ comes out to be
λ₂ = 2·08 × 10⁻⁴ (sec)⁻¹.
This value of λ₂ corresponds to a change in which half the matter is
transformed in 55 minutes.
Substituting now the values of λ₁, λ₂, _T_, the equation reduces to
$$ \frac {I_t} {I_T} = 1\cdot37 (e^{–λ_2 t} − e^{–λ_2 t}) $$ .
The agreement between the results of the theoretical equation and the
observed values is shown in the following table:
Time in Theoretical Observed value
minutes value of of
_I_{t}_/_I_{T}_ _I_{t}_/_I_{T}_
15 ·22 ·23
30 ·38 ·37
60 ·64 ·63
120 ·90 ·91
220 1·00 1·00
305 ·97 ·96
After 5 hours the activity decreased nearly exponentially with the time,
falling to half value in 11 hours.
It is thus seen that the curve of rise of activity for a short exposure
is explained very satisfactorily on the supposition that two changes
occur in the deposited matter, of which the first is a rayless change.
Public-domain text, read in full here on John Shaqi.
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