Further data are required in order to fix which of the time constants of
the changes refers to the first change. In order to settle this point,
it is necessary to isolate one of the products of the changes and to
examine the variation of its activity with time. If, for example, a
product can be separated whose activity decays to half value in 55
minutes, it would show that the second change is the more rapid of the
two. Now Pegram[302] has examined the radio-active products obtained by
electrolysis of thorium solutions. The rates of decay of the active
products depended upon conditions, but he found that, in several cases,
rapidly decaying products were obtained whose activity fell to half
value in about 1 hour. Allowing for the probability that the product
examined was not completely isolated by the electrolysis, but contained
also a trace of the other product, this result would indicate that the
last change which gives rise to rays is the more rapid of the two.
This point is very clearly brought out by some recent experiments of
Miss Slater[303], who has made a detailed examination of the effect of
temperature on the active deposit of thorium.
A platinum wire was made active by exposure for a long interval to the
thorium emanation, and then heated for a few minutes to any desired
temperature by means of the electric current. The wire, while being
heated, was surrounded by a lead cylinder in order that any matter
driven off from it should be collected on its surface. The decay of
activity both of the wire and of the lead cylinder was then tested
separately. After heating to a dull red heat, no sensible diminution of
the activity was observed at first, but the rate of decay of the
activity on the wire was found to be more rapid than the normal. The
activity of the lead cylinder was small at first but increased to a
maximum after about 4 hours and then decayed at the normal rate with the
time.
These results are to be expected if some thorium A is volatilized from
the wire; for the rise of activity on the lead cylinder is very similar
to that observed on a wire exposed for a short time in the presence of
the thorium emanation, _i.e._, under the condition that only thorium A
is initially present.
On heating the wire above 700° C. the activity was found to be reduced,
showing that some thorium B had also been removed. By heating for a few
minutes at about 1000° C. nearly all the thorium A was driven off. The
activity on the wire then decayed exponentially with the time, falling
to half value in about 1 hour. After heating for a minute at about 1200°
C. all the activity was removed. These results show that thorium A is
more volatile than B, and that the product which gives out rays, viz.
thorium B, has a period of about 55 minutes.
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