The differences in the last three numbers are not significant, for it is
difficult to make accurate comparisons of the activity of thorium
compounds which have been precipitated under slightly different
conditions. It is thus seen that as a result of successive
precipitations, the activity is reduced to a minimum of about 25 per
cent. The recovery curve of the activity of this 23 times precipitated
hydroxide is shown in Fig. 79. The initial drop in the curve is quite
absent, and the curve, starting from the minimum, is practically
identical with the curve shown in Fig. 48, which gives the recovery
curve of thorium hydroxide after the first two days. This residual
activity—about 25 per cent. of the maximum—is non-separable from the
thorium by any chemical process that has been tried.
The initial rise of activity of Th X, after it has been separated, will
now be considered. In all cases it was found that the activity of the
separated Th X had increased about 15 per cent. at the end of 24 hours,
and then steadily decayed, falling to half value in about four days.
This peculiarity of the Th X curve follows, of necessity, from the
considerations already advanced to explain the drop in the recovery
curve. As soon as the Th X is separated, it at once produces from itself
the emanation, and this in turn produces thorium A and B. The activity
due to B at first more than compensates for the decay of activity of the
Th X itself. The total activity thus increases to a maximum, and then
slowly decays to zero according to an exponential law with the time. The
curve expressing the variation of the activity of the separated Th X
with time can be deduced from the theory of successive changes already
considered in chapter IX. In the present case there are four successive
changes occurring at the same time, viz. the change of Th X into the
emanation, of the emanation into thorium A, of A into B, and of B into
an inactive product. Since, however, the change of the emanation into
thorium A (about half changed in one minute) is far more rapid than the
changes occurring in Th X or thorium A and B, for the purposes of
calculation it may be assumed without serious error that the Th X
changes at once into the active deposit. The 55 minute change will also
be disregarded for the same reason.
Let λ₁ and λ₂ be the constants of decay of activity of Th X and of
thorium A respectively. Since the activity of Th X and of thorium A
falls to half value in 4 days and 11 hours respectively, the value of λ₁
= ·0072 and of λ₂ = ·063, where 1 hour is taken as the unit of time.
The problem reduces to the following: _Given the matter A (thorium X)
all of one kind, which changes into B (thorium B), find the activity of
A and B together at any subsequent time._ This corresponds to Case I.
(section 197). The amount _Q_ of B at any time _T_ is given by
$$ Q = \frac {λ_1 n₀} {λ_1 − λ_2} (e^{–λ_2 t} -
e^{–λ_1 t}) $$,
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