and the activity _I_ at any time of the two together is proportional to
λ₁_P_ + _K_λ₂_Q_, where _K_ is the ratio of the ionization of B compared
with that of A.
Then
$$ \frac {I_t} {I₀} = \frac {λ_1 P + Kλ_2 Q} {λ_1
n₀} $$
$$ = e^{–λ_1 t} (1 + \frac {Kλ_2} {λ_2 − λ_1}
(1 − e^{-(λ_2 − λ_1) t})) $$,
where _I₀_ is the initial activity due to _n₀_ particles of Th X.
By comparison of this equation with the curve of variation of the
activity of Th X with time, shown in Fig. 47, it is found that _K_ is
almost ·44. It must be remembered that the activity of the emanation and
Th X are included together, so that the activity of thorium B is about
half of the activity of the two preceding products.
The calculated values of _I_{t}_/_I₀_ for different values of _t_ are
shown in the second column of the following table, and the observed
values in the third column.
Time Theoretical Observed
value value
0 1·00 1·00
·25 days 1·09 —
·5 „ 1·16 —
1 „ 1·15 1·17
1·5 „ 1·11 —
2 „ 1·04 —
3 „ ·875 ·88
4 „ ·75 ·72
6 „ ·53 ·53
9 „ ·315 ·295
13 „ ·157 ·152
[Illustration: Fig. 80.]
The theoretical and observed values thus agree within the limit of error
in the measurements. The theoretical curve is shown in Curve _A_, Fig.
80 (with the observed points marked, for comparison). The curve _B_
shows the theoretical curve of the decay of the activity of Th X and the
emanation, supposing there is no further change into the active deposit.
Curve _C_ shows the difference curve between the curves _A_ and _B_,
_i.e._ the proportion of the activity at different times due to the
active deposit. The activity due to the latter thus rises to a maximum
about two days after removal of the Th X, and then decays with the time
at the same rate as the Th X itself, _i.e._ the activity falls to half
value every four days. When _t_ exceeds four days, the term
$$ e^{-(λ_2 − λ_1) t} $$
in the theoretical equation is very small.
The equation of decay after this time is therefore expressed by
$$ \frac {I_t} {I₀} = (1 + \frac {Kλ_2} {λ_2 − λ_1})
e^{–λ_1 t} $$,
_i.e._ the activity decays according to an exponential law with the
time.
Public-domain text, read in full here on John Shaqi.
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