=209. Radiations from Thorium products.= It has been shown in the last
section that the activity of thorium, by successive precipitations with
ammonia, is reduced to a limiting value of almost 25 per cent. of the
initial activity. This “non-separable activity” consists of α rays, the
β and γ rays being altogether absent. According to the disintegration
theory, this is an expression of the fact that the initial break-up of
the thorium atom is accompanied only by the expulsion of α particles. We
have seen in section 156 that the thorium emanation also gives out only
α rays. In the active deposit, thorium A gives out no rays, while
thorium B emits all three types of rays.
Some hours after separation, Th X gives out α, β, and γ rays, but the
appearance of β and γ rays is probably due to the thorium B associated
with it. The β and γ ray activity of Th X is much reduced if a current
of air is continuously aspirated through a solution of Th X to remove
the emanation. It seems likely that if the emanation could be removed as
fast as it was formed, so as to prevent the formation of thorium B in
its mass, Th X itself would give out only α rays: but, on account of the
rapid rate of change of the thorium emanation, it is difficult to
realize this experimentally.
=210. Transformation products of Thorium.= The transformation products
of thorium and the rays emitted by them are graphically shown below
(Fig. 81).
[Illustration: Fig. 81.]
A table of the transformation products of thorium is shown below, with
some of their physical and chemical properties.
Product Time to be λ (sec)⁻¹ Radiations Physical and
half chemical
transformed properties
Thorium α rays Insoluble in
ammonia
Th. X 4 days 2·00 × α rays Soluble in
10⁻⁶ ammonia
Emanation 54 secs. 1·28 × α rays Inert gas,
10⁻² condenses
−120° C.
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